Multiple functional ionic liquids based dispersive liquid-liquid microextraction combined with high performance chromatography for the determination of phenolic compounds in water samples | |
Department | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Sun JN(孙建楠)1,2; Chen J(陈娟)1; Shi YP(师彦平)1; Chen J(陈娟); Shi YP(师彦平) | |
2014 | |
Source Publication | Talanta |
ISSN | 0039-9140 |
Volume | 125Pages:329-335 |
Abstract | A new mode of ionic liquid based dispersive liquid–liquid microextraction (IL-DLLME) is developed. In this work, [C6MIm][PF6] was chosen as the extraction solvent, and two kinds of hydrophilic ionic liquids, [EMIm][BF4] and [BSO3HMIm][OTf], functioned as the dispersive solvent. So in the whole extraction procedure, no organic solvent was used. With the aid of SO3H group, the acidic compound was extracted from the sample solution without pH adjustment. Two phenolic compounds, namely, 2-naphthol and 4-nitrophenol were chosen as the target analytes. Important parameters affecting the extraction efficiency, such as the type of hydrophilic ionic liquids, the volume ratio of [EMIm][BF4] to [BSO3HMIm][OTf], type and volume of extraction solvent, pH value of sample solution, sonication time, extraction time and centrifugation time were investigated and optimized. Under the optimized extraction conditions, the method exhibited good sensitivity with the limits of detection (LODs) at 5.5 μg L_1and 10.0 μg L_1 for 4-nitrophenol and 2-naphthol, respectively. Good linearity over the concentration ranges of 24–384 μg L_1 for 4-nitrophenol and 28–336 μg L_1 for 2-naphthol was obtained with correlation coefficients of 0.9998 and 0.9961, respectively. The proposed method can directly extract acidic compound from environmental sample or even more complex sample matrix without any pH adjustment procedure. |
Keyword | Hydrophilic Ionic Liquid Dispersive Liquid-liquid Microextraction Hplc Phenolic Compound Environmental Water Samples |
Subject Area | 分析化学与药物化学 |
DOI | 10.1016/j.talanta.2014.03.013 |
Funding Organization | the National Nature Science Foundation of China (Nos. 21105106;21375136);Natural Science Foundation of Gansu Province (No.1107RJZA146) |
Indexed By | SCI |
If | 3.545 |
Language | 英语 |
Funding Project | 药物化学成分研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/6932 |
Collection | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Corresponding Author | Chen J(陈娟); Shi YP(师彦平) |
Affiliation | 1.Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, People׳s Republic of China 2.Graduate University of Chinese Academy of Sciences, Beijing 100039, People׳s Republic of China |
Recommended Citation GB/T 7714 | Sun JN,Chen J,Shi YP,et al. Multiple functional ionic liquids based dispersive liquid-liquid microextraction combined with high performance chromatography for the determination of phenolic compounds in water samples[J]. Talanta,2014,125:329-335. |
APA | Sun JN,Chen J,Shi YP,陈娟,&师彦平.(2014).Multiple functional ionic liquids based dispersive liquid-liquid microextraction combined with high performance chromatography for the determination of phenolic compounds in water samples.Talanta,125,329-335. |
MLA | Sun JN,et al."Multiple functional ionic liquids based dispersive liquid-liquid microextraction combined with high performance chromatography for the determination of phenolic compounds in water samples".Talanta 125(2014):329-335. |
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