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Tribological Properties of Thermosetting Polyimide/TiO2 Nanocomposites Under Dry Sliding and Water-Lubricated Conditions
Department先进润滑与防护材料研究发展中心
Liu H(刘洪); Wang TM(王廷梅); Wang QH(王齐华); Wang QH(王齐华)
The second department固体润滑国家重点实验室
2012
Source PublicationJournal of Macromolecular Science Part B Physics
ISSN0022-2348
Volume51Issue:11Pages:2284-2296
AbstractThermosetting polyimide(PI)-based nanocomposites containing various contents of nano-TiO2 were fabricated via an in situ polymerization of monomer reactants (PMR) process. Under dry sliding and water-lubricated conditions the friction and wear behaviors of the PMR PI and its nanocomposites were evaluated and compared. The addition of nano-TiO2 in PI contributed to improving the friction and wear behavior considerably under dry sliding. The highest change ratio of wear rate was 61% with the optimum nano-TiO2 content of 3%, while the highest change of friction coefficient was 60% with the optimum nano-TiO2 content of 9%. Under water-lubricated condition, contrarily, the addition of nano-TiO2 in PI does harm to the tribological properties. Namely, the friction coefficient of the nanocomposites increased with increasing the nano-TiO2 content. These results may be caused by the following facts: the hardness of the PI matrix would be increased by adding the nano-TiO2 reducing the ability of elastic deformation of the nanocomposites; accordingly, the poor elastic deformation hindered the formation of a water-lubrication film on the surface. An investigation on the wear tracks indicated that the wear mechanism of PI/TiO2 nanocomposites under dry sliding condition proceeded from fatigue wear to a combination of fatigue wear and abrasive wear with increasing the mass fraction of nano-TiO2.
KeywordNano-tio2 Nanocomposites Pmr Thermosetting Polyimide Tribological Properties
Subject Area材料科学与物理化学
DOI10.1080/00222348.2011.624043
Funding Organizationthe National Natural Science Foundation of China (Grant No. 50805139)
Indexed BySCI
If0.628
Language英语
Funding Project聚合物自润滑复合材料组
compositor第一作者单位
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/3362
Collection固体润滑国家重点实验室(LSL)
中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心
Corresponding AuthorWang QH(王齐华)
AffiliationChinese Acad Sci, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Liu H,Wang TM,Wang QH,et al. Tribological Properties of Thermosetting Polyimide/TiO2 Nanocomposites Under Dry Sliding and Water-Lubricated Conditions[J]. Journal of Macromolecular Science Part B Physics,2012,51(11):2284-2296.
APA Liu H,Wang TM,Wang QH,&王齐华.(2012).Tribological Properties of Thermosetting Polyimide/TiO2 Nanocomposites Under Dry Sliding and Water-Lubricated Conditions.Journal of Macromolecular Science Part B Physics,51(11),2284-2296.
MLA Liu H,et al."Tribological Properties of Thermosetting Polyimide/TiO2 Nanocomposites Under Dry Sliding and Water-Lubricated Conditions".Journal of Macromolecular Science Part B Physics 51.11(2012):2284-2296.
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