Damping, Thermal, and Mechanical Properties of Polycaprolactone-Based PU/EP Graft IPNs: Effects of Composition and Isocyanate Index | |
Department | 先进润滑与防护材料研究发展中心 |
Chen SB(陈守兵)1,2; Wang QH(王齐华)1; Wang TM(王廷梅)1; Wang TM(王廷梅) | |
The second department | 固体润滑国家重点实验室 |
2012 | |
Source Publication | Journal of Macromolecular Science Part B-Physics |
ISSN | 0022-2348 |
Volume | 51Issue:1-3Pages:83-95 |
Abstract | A series of polycaprolactone (PCL)-based polyurethane (PU)/epoxy resin (EP) graft interpenetrating polymer networks (IPNs) were prepared and their damping propertiesand thermal stability, as well as mechanical properties, were systematically studied in terms of composition and the values of the PU isocyanate index (R). The morphologies of the PU/EP IPNs were observed by scanning electron microscope (SEM) and atomic force microscope (AFM) characterization and the relationship between the morphologies and the properties is also discussed. The damping properties and thermal stability measurements revealed that the formation of PU/EP IPNs could significantly improve not only the damping properties but also the thermal stability. Meanwhile, the mechanical tests showed that the tensile strengths of the IPNs decreased, while their impact strengths increased with increasing PU content. The value of the PU isocyanate index also had significant impacts on the properties of the IPNs when the PU to EP ratio was fixed, which could be an effective means for manipulating the fabrication of PU/EP IPNs. From the results obtained, the PCL-based PU/EP IPNs hold promise for use in structural damping materials. |
Keyword | Damping Properties Interpenetrating Polymer Networks (Ipns) Isocyanate Index Polycaprolactone-based Polyurethane Pu/ep |
Subject Area | 材料科学与物理化学 |
DOI | 10.1080/00222348.2011.565266 |
Funding Organization | the National Science Foundation for Distinguished YoungScholars of China (grant no. 51025517);the Innovative Group Foundation of NSFC (grantno. 50721062);the 973 Project of China (2007CB607606) |
Indexed By | SCI |
If | 0.628 |
Language | 英语 |
Funding Project | 聚合物自润滑复合材料组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/3360 |
Collection | 固体润滑国家重点实验室(LSL) 中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心 |
Corresponding Author | Wang TM(王廷梅) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing, Peoples R China |
Recommended Citation GB/T 7714 | Chen SB,Wang QH,Wang TM,et al. Damping, Thermal, and Mechanical Properties of Polycaprolactone-Based PU/EP Graft IPNs: Effects of Composition and Isocyanate Index[J]. Journal of Macromolecular Science Part B-Physics,2012,51(1-3):83-95. |
APA | Chen SB,Wang QH,Wang TM,&王廷梅.(2012).Damping, Thermal, and Mechanical Properties of Polycaprolactone-Based PU/EP Graft IPNs: Effects of Composition and Isocyanate Index.Journal of Macromolecular Science Part B-Physics,51(1-3),83-95. |
MLA | Chen SB,et al."Damping, Thermal, and Mechanical Properties of Polycaprolactone-Based PU/EP Graft IPNs: Effects of Composition and Isocyanate Index".Journal of Macromolecular Science Part B-Physics 51.1-3(2012):83-95. |
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83-95.PDF(916KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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