Titanium-Catalyzed Direct Synthesis of 1,1-Diborylalkanes from Aryl Alkenes | |
Department | 羰基合成与选择氧化国家重点实验室(OSSO) |
Li SD(李思达)1,2,3; Cui X(崔鑫)1; Shu XZ(舒兴中)2; Wu LP(吴立朋)1 | |
The second department | 吴立朋人才团队 |
2023-10-12 | |
Source Publication | Chin. J. Org. Chem. |
Issue | 43Pages:1-7 |
Abstract | 开发了一种适用范围广且在温和条件下就可以进行的芳基烯烃和频哪醇硼烷(HBpin)之间1,1-二硼化反应制备1,1-二硼化合物的新方法。成功的关键是利用丰产金属钛(Cp2TiCl2)作为催化剂,并且在甲醇锂(MeOLi)的活化作用下进行。我们推测由Cp2TiCl2/MeOLi/HBpin体系中原位生成的Ti-H物种是催化该反应进行的主要活性物种。 |
Keyword | 钛 催化 烯烃 1,1-二硼化 |
MOST Discipline Catalogue | 理学::化学 |
DOI | 10.6023/cjoc202309021. |
URL | 查看原文 |
Indexed By | SCI |
If | 1.9 |
Language | 英语 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/30582 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Li SD(李思达); Wu LP(吴立朋) |
Affiliation | 1.中国科学院兰州化学物理研究所 2.兰州大学 3.中国科学院大学 |
Corresponding Author Affilication | Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences |
Recommended Citation GB/T 7714 | Li SD,Cui X,Shu XZ,et al. Titanium-Catalyzed Direct Synthesis of 1,1-Diborylalkanes from Aryl Alkenes[J]. Chin. J. Org. Chem.,2023(43):1-7. |
APA | Li SD,Cui X,Shu XZ,&Wu LP.(2023).Titanium-Catalyzed Direct Synthesis of 1,1-Diborylalkanes from Aryl Alkenes.Chin. J. Org. Chem.(43),1-7. |
MLA | Li SD,et al."Titanium-Catalyzed Direct Synthesis of 1,1-Diborylalkanes from Aryl Alkenes".Chin. J. Org. Chem. .43(2023):1-7. |
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钛催化的烯烃制备1,1-二硼化合物.pd(896KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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