Plant Leaf-Inspired Separators with Hierarchical Structure and Exquisite Fluidic Channels for Dendrite-Free Lithium Metal Batteries | |
Department | 环境材料与生态化学研究发展中心 |
Yang, Yanfei1; Wang, Wankai1,3; Li, Meisheng2; Zhou, Shouyong2; Zhang, Junping1,3; Wang, Aiqin1,3 | |
The second department | 硅基功能材料组 |
2023-04-27 | |
Source Publication | Small |
Issue | 19Pages:2301237 |
Abstract | Lithium (Li) metal batteries are among the most promising devices for high energy storage applications but suffer from severe and irregular Li dendrite growth. Here, it is demonstrated that the issue can be well tackled by precisely designing the leaf-like membrane with hierarchical structure and exquisite fluidic channels. As a proof of concept, plant leaf-inspired membrane (PLIM) separators are prepared using natural attapulgite nanorods. The PLIM separators feature super-electrolyte-philicity, high thermal stability and high ion-selectivity. Thus, the separators can guide uniform and directed Li growth on the Li anode. The Li//PLIM//Li cell with limited Li anode shows high Coulombic efficiency and cycling stability over 1500 h with small overpotential and interface impedance. The Li//PLIM//S battery exhibits high initial capacity (1352 mAh g−1), cycling stability (0.019% capacity decay per cycle at 1 C over 500 cycles), rate performance (673 mAh g−1 at 4 C), and high operating temperature (65 °C). The separators can also effectively improve reversibility and cycling stability of the Li/Li cell and Li//LFP battery with carbonate-based electrolyte. As such, this work provides fresh insights into the design of bioinspired separators for dendrite-free metal batteries. |
Keyword | Attapulgite Dendrite-free Exquisite fluidic channels Hierarchical structures Leaf-inspired separators |
DOI | DOI: 10.1002/smll.202301237 |
Indexed By | SCI |
If | 13.3 |
Language | 英语 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/30169 |
Collection | 环境材料与生态化学研究发展中心 |
Corresponding Author | Zhou, Shouyong; Zhang, Junping |
Affiliation | 1.Key Laboratory of Clay Mineral Applied Research of Gansu Province, and Center of Eco-Material and Green Chemistry Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000, P. R. China 2.Jiangsu Engineering Laboratory for Environmental Functional Materials Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials School of Chemistry and Chemical Engineering Huaiyin Normal University Huaian 223300, P. R. China 3.Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing 100049, P. R. China |
Recommended Citation GB/T 7714 | Yang, Yanfei,Wang, Wankai,Li, Meisheng,et al. Plant Leaf-Inspired Separators with Hierarchical Structure and Exquisite Fluidic Channels for Dendrite-Free Lithium Metal Batteries[J]. Small,2023(19):2301237. |
APA | Yang, Yanfei,Wang, Wankai,Li, Meisheng,Zhou, Shouyong,Zhang, Junping,&Wang, Aiqin.(2023).Plant Leaf-Inspired Separators with Hierarchical Structure and Exquisite Fluidic Channels for Dendrite-Free Lithium Metal Batteries.Small(19),2301237. |
MLA | Yang, Yanfei,et al."Plant Leaf-Inspired Separators with Hierarchical Structure and Exquisite Fluidic Channels for Dendrite-Free Lithium Metal Batteries".Small .19(2023):2301237. |
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Small - 2023 - Yang.(3039KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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