KMS Lanzhou Institute of Chemical Physics，Chinese Academy of Sciences
| Visible-Light-Promoted Photoredox Dehydrogenative Coupling of Phosphines and Thiophenols | |
| Department | 羰基合成与选择氧化国家重点实验室（OSSO） |
Wang XY(王显亚)1,2; Xia CG(夏春谷)1 ; Wu LP(吴立朋)1
| |
| The second department | 吴立朋人才团队 |
| 2020-09 | |
| Source Publication | Org. Lett
 |
| Issue | 22Pages:7373 |
| Abstract | Herein, by applying visible-light photoredox catalysis, we have now achieved the first example of catalytic dehydrogenative coupling of phosphines and thiophenols that proceeds at room temperature. Key to our success is the use of benzaldehyde as a soft oxidant, which avoids the issue of phosphine oxidation. Furthermore, we observed the unexpected dealkylative coupling of secondary and tertiary alkylphosphine with thiophenols. |
| URL | 查看原文 |
| Indexed By | SCI |
| If | 6.091 |
| Language | 英语 |
| compositor | 第一作者单位 |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/26974 |
| Collection | 中国科学院兰州化学物理研究所 |
| Corresponding Author | Wang XY(王显亚); Wu LP(吴立朋) |
| Affiliation | 1.兰州化物所 2.中国科学院大学 |
| Recommended Citation GB/T 7714 | Wang XY,Xia CG,Wu LP. Visible-Light-Promoted Photoredox Dehydrogenative Coupling of Phosphines and Thiophenols[J]. Org. Lett,2020(22):7373. |
| APA | Wang XY,Xia CG,&Wu LP.(2020).Visible-Light-Promoted Photoredox Dehydrogenative Coupling of Phosphines and Thiophenols.Org. Lett(22),7373. |
| MLA | Wang XY,et al."Visible-Light-Promoted Photoredox Dehydrogenative Coupling of Phosphines and Thiophenols".Org. Lett .22(2020):7373. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| acs.orglett.0c02746.（1334KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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