Hydrogen generation from toxic formaldehyde catalyzed by low-cost Pd–Sn alloys driven by visible light | |
Department | 羰基合成与选择氧化国家重点实验室(OSSO) |
Hongxia Liu1,2,3; Meng Wang1,2,3; Jiantai Ma3; Gongxuan Lu1 | |
The second department | 环境催化与氢能 |
2020-05 | |
Source Publication | Journal of Materials Chemistry A |
Volume | 8Issue:19Pages:9616-9628 |
Abstract | Noble metal co-catalysts are efficient for photocatalytic hydrogen generation from formaldehyde, but their high cost and low abundance limit their scale-up applications. Alloying a second metal with noble metals offers an available way to decrease their usage and consumption and enhances their catalytic activity. Among the potential candidates, Sn is a high abundance element in the earth. In this work, a new highly active low-cost Pd–Sn/RGO catalyst has been developed. Under optimized conditions, the hydrogen evolution rate reached up to 530.07 μmol h−1 driven by visible light. By taking advantage of the optimized adsorption nature of the active sites on the alloy cocatalyst, effective separation and transfer of photogenerated charges have been achieved; at the same time, the photo-generated electrons have a longer lifetime. More interestingly, it has been found that trace amounts of oxygen are helpful in catalytic hydrogen production from HCHO. |
Indexed By | SCI ; EI |
If | 11.301 |
Language | 英语 |
compositor | 第一作者单位 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/26578 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) 中国科学院兰州化学物理研究所 |
Corresponding Author | Gongxuan Lu |
Affiliation | 1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China 2.University of Chinese Academy of Sciences, Beijing 100049, China 3.College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, 730000, China |
Recommended Citation GB/T 7714 | Hongxia Liu,Meng Wang,Jiantai Ma,等. Hydrogen generation from toxic formaldehyde catalyzed by low-cost Pd–Sn alloys driven by visible light[J]. Journal of Materials Chemistry A,2020,8(19):9616-9628. |
APA | Hongxia Liu,Meng Wang,Jiantai Ma,&Gongxuan Lu.(2020).Hydrogen generation from toxic formaldehyde catalyzed by low-cost Pd–Sn alloys driven by visible light.Journal of Materials Chemistry A,8(19),9616-9628. |
MLA | Hongxia Liu,et al."Hydrogen generation from toxic formaldehyde catalyzed by low-cost Pd–Sn alloys driven by visible light".Journal of Materials Chemistry A 8.19(2020):9616-9628. |
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File Name/Size | DocType | Version | Access | License | ||
2020, 8(19),9616-962(2448KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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