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Soft-nanocomposite lubricants of supramolecular gel with carbon nanotubes
Department固体润滑国家重点实验室
Yanyan, Bai1,2; Qiangliang, Yu1; Jiaying, Zhang1; Meirong, Cai1; Yongmin, Liang3; Feng, Zhou1; Weimin, Liu1
The second department材料表界面课题组
2019-02-13
Source PublicationJournal of materials chemistry A
Issue7Pages:7654–7663
Abstract

Carbon nanotubes (CNTs) have been the focus of much research due to their excellent lubricity and antiwear properties. However, when they are used as lubricating oil additives, they tend to agglomerate and precipitate, because of which achieving good dispersion stability is a significant problem. This manuscript reports a new strategy to successfully resolve the problem of poor dispersion stability of CNTs in the lubricating material 12-hydroxystearic acid (12-HSA) supramolecular gel. On the one hand, the carbon nanotubes are trapped in the network of the supramolecular gel which greatly reduces its reaggregation
in the 500SN base oil. On the other hand, the carbon nanotubes significantly improved the thermal, mechanical and tribological properties of the supramolecular gel. For example, the decomposition
temperature is increased by 30 C as the 500SN base oil molecules are trapped in the 3-D network of supramolecules. The viscoelasticity of the supramolecular gel is improved when the carbon nanotubes
are used as additives. The results also show that a small quantity of modified carbon nanotubes as additives can significantly reduce friction and wear. And the CNTs and acidified carbon nanotubes (CNTHs) can provide the same friction coefficient as both of them are trapped in the 3-D network of the quasi-solid state 12-HSA soft-nanocomposite. In addition, we performed experiments and molecular dynamics simulations to explore the microstructure and self-assembly mechanism of the softnanocomposite lubricant. The soft-nanocomposite lubricant not only prolonged the useful life of machinery, but also reduced the waste of resources, which is significant in sustainable development.

MOST Discipline Catalogue理学
DOI10.1039/c8ta11051d
Indexed BySCI
If10.733
Language英语
compositor第一作者单位
Citation statistics
Cited Times:34[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/26244
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorMeirong, Cai; Weimin, Liu
Affiliation1.State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences
2.University of Chinese Academy of Sciences
3.State Key Laboratory of Applied Organic Chemistry, Lanzhou University
Recommended Citation
GB/T 7714
Yanyan, Bai,Qiangliang, Yu,Jiaying, Zhang,et al. Soft-nanocomposite lubricants of supramolecular gel with carbon nanotubes[J]. Journal of materials chemistry A,2019(7):7654–7663.
APA Yanyan, Bai.,Qiangliang, Yu.,Jiaying, Zhang.,Meirong, Cai.,Yongmin, Liang.,...&Weimin, Liu.(2019).Soft-nanocomposite lubricants of supramolecular gel with carbon nanotubes.Journal of materials chemistry A(7),7654–7663.
MLA Yanyan, Bai,et al."Soft-nanocomposite lubricants of supramolecular gel with carbon nanotubes".Journal of materials chemistry A .7(2019):7654–7663.
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