羰基合成与选择氧化国家重点实验室（OSSO）知识库

For lithium thionyl chloride batteries, the catalytic activity of the cathode material plays a crucial role in its electrochemical performance.
In this paper, a poly (1-vinyl-3-methylimidazolium dicyanamide) ionic liquid (PIL) is selected as precursor to support CuO
nanoparticles, and an efficient, non-precious metal nitrogen doped carbon supported Cu nanoparticles (N-C@Cu) composite material
is designed and prepared for the lithium thionyl chloride battery cathode catalyst. X-ray diffraction (XRD) and high-resolution
transmission electron microscope (HRTEM) verified that the supported CuO nanoparticles is reduced to Cu via carbon which formed
from the thermally decompose of PIL. X-ray photoelectron spectroscopy (XPS) images confirm the existence of nitrogen doped
carbon and Cu nanoparticles. Raman spectroscopy also demonstrate that the interaction between Cu and N-C provides more active
sites. The N-C@Cu composite catalyst exhibits excellent activity in the reduction process of thionyl chloride, as can be seen from
the materials display characteristics of lower discharge over-potential, and improved electron transfer of its rate-determining step.
The rate performance, operating voltage and discharge capacity are all improved.