| Benzimidazole functionalized covalent triazine frameworks for CO2 capture | |
| Department | 先进润滑与防护材料研究发展中心 |
Tao LM(陶立明)1 ; Niu F(牛芳)2; Wang C(王超)1; Liu, Jingang3; Wang TM(王廷梅)1; Wang QH(王齐华)1; Wang QH(王齐华)
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| The second department | 固体润滑国家重点实验室 |
| 2016 | |
| Source Publication | Journal of Materials Chemistry A
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| ISSN | 2050-7488 |
| Volume | 4Issue:30Pages:11812-11820 |
| Abstract | A series of covalent triazine frameworks containing benzimidazole segments (CTF-BIs) were designed and prepared by dynamic trimerization under ionothermal conditions, based on the novel designed dicyano monomer of dicyano benzimidazole (DCBI). The CTF-BIs were all amorphous and exhibited BET surface areas up to 1549 m2 g−1. The effect of reaction conditions including the ratio of catalyst and temperature on the pore properties was discussed. Meanwhile, the CO2 adsorption capacity of all the CTF-BIs was studied and it was found that the CO2 uptake capacity was as high as 21.68 wt% at 273 K and 1.10 bar for CTF-BI-11. The CTF-BIs exhibited high selectivities for CO2 over N2 in the range of 31.3–88.5 at 273 K, and 29.0–102.7 at 303 K, respectively. |
| Subject Area | 材料科学与物理化学 |
| DOI | 10.1039/c6ta05107c |
| Funding Organization | the National Natural Science Foundation of China (No. 51103168;21201093;51403219);the Fundamental Research Funds for the Central Universities (No. lzujbky-2014-72) |
| Indexed By | SCI |
| If | 8.867 |
| Language | 英语 |
| Funding Project | 聚合物自润滑复合材料组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/20314 |
| Collection | 中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Wang QH(王齐华) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Gansu, Peoples R China 2.Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China 3.Chinese Acad Sci, Inst Chem, Lab Adv Polymer Mat, Beijing 100866, Peoples R China |
| Recommended Citation GB/T 7714 | Tao LM,Niu F,Wang C,et al. Benzimidazole functionalized covalent triazine frameworks for CO2 capture[J]. Journal of Materials Chemistry A,2016,4(30):11812-11820. |
| APA | Tao LM.,Niu F.,Wang C.,Liu, Jingang.,Wang TM.,...&王齐华.(2016).Benzimidazole functionalized covalent triazine frameworks for CO2 capture.Journal of Materials Chemistry A,4(30),11812-11820. |
| MLA | Tao LM,et al."Benzimidazole functionalized covalent triazine frameworks for CO2 capture".Journal of Materials Chemistry A 4.30(2016):11812-11820. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c6ta05107c.pdf（679KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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