| Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by Pd (OAc)2/SO under solvent-free conditions | |
| Department | 羰基合成与选择氧化国家重点实验室 ; 绿色化学研究发展中心 |
Liu JH(刘俊华); Wang F(王丰); Sun KP(孙鲲鹏) ; Xu XL(徐贤伦)
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| 2008 | |
| Source Publication | Catalysis Communications
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| ISSN | 1566-7367 |
| Volume | 9Pages:386-390 |
| Abstract | With oxygen that was supplied by hydrogen peroxide as oxidant, secondary and primary aliphatic alcohols, primary allylic alcohols could be efficiently oxidized to aldehydes or ketones in high yields in the presence of Pd (OAc)2 sodium oxalate (SO) under solvent-free conditions, it is a high yielding and operationally simple method. Acetic acid is testified to attend the reaction, the acetate ligands are environed to serve two purposes: as a ligand for the PdII center and as a base to deprotonate the Pd-bound alcohol, but acetic acid has not shown in previous bidentate ligands systems, so a mechanism is proposed on the basis of the mechanisms reported by the pioneers. |
| Keyword | Alcohols Aldehydes Hydrogen Peroxide Oxidation Palladium Sodium Oxalate |
| Subject Area | 物理化学 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 精细石油化工催化课题组 |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/1986 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 绿色化学研究发展中心 |
| Corresponding Author | Xu XL(徐贤伦) |
| Recommended Citation GB/T 7714 | Liu JH,Wang F,Sun KP,et al. Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by Pd (OAc)2/SO under solvent-free conditions[J]. Catalysis Communications,2008,9:386-390. |
| APA | 刘俊华,王丰,孙鲲鹏,&徐贤伦.(2008).Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by Pd (OAc)2/SO under solvent-free conditions.Catalysis Communications,9,386-390. |
| MLA | 刘俊华,et al."Effective oxidation of alcohols to aldehydes with hydrogen peroxide catalyzed by Pd (OAc)2/SO under solvent-free conditions".Catalysis Communications 9(2008):386-390. |
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| 44_Catal.Commun.,200（137KB） | 开放获取 | License | View Application Full Text | |||
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