A facile synthesis of cost-effective triphenylamine-containing porous organic polymers using different crosslinkers | |
Department | 先进润滑与防护材料研究发展中心 |
Zhang D(张迪)1,2; Tao LM(陶立明)1; Wang QH(王齐华)1; Wang TM(王廷梅)1; Wang TM(王廷梅) | |
The second department | 固体润滑国家重点实验室 |
2016 | |
Source Publication | Polymer |
ISSN | 0032-3861 |
Volume | 82Pages:114-120 |
Abstract | The synthesis of polytriphenylamine networks (PTPAs) was accomplished by FeCl3-promoted one-step oxidative coupling reaction and Friedel–Crafts alkylation in one pot. For the first time, we used the common reagents including trimethyl orthoformate (TMOF), trimethyl orthoacetate (TMOA), triethyl orthoacetate (TEOA) and triisopropyl orthoformate (TIPO) as the crosslinkers, respectively. The highest BET specific surface area is 1543 m2 g−1, for PTPA-4. Its CO2 uptake capacity is as high as 2.65 mmol g−1 at 1.0 bar and 273 K, which makes it promising candidate for applications in environment fields. In addition, this work extends the types of cheap crosslinkers that could be incorporated into porous organic polymers to enhance their porosity. |
Keyword | Porous Organic Polymers (Pops) Hyper-crosslinked Polymers (Hcps) Capture And Storage Of Co2 |
Subject Area | 材料科学与物理化学 |
DOI | 10.1016/j.polymer.2015.11.041 |
Funding Organization | the National Defense Innovation Fund of Chinese Academy of Sciences (CXJJ-14-M43);the National Basic Research Program of China (973 program, Grant No. 2015CB057502);Nature Science Foundation of China (NSFC) (Grant No. 51103168;Grant No.51403219;51303189) |
Indexed By | SCI |
If | 3.684 |
Language | 英语 |
Funding Project | 聚合物自润滑复合材料组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/19458 |
Collection | 中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心 固体润滑国家重点实验室(LSL) |
Corresponding Author | Wang TM(王廷梅) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Gansu, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
Recommended Citation GB/T 7714 | Zhang D,Tao LM,Wang QH,et al. A facile synthesis of cost-effective triphenylamine-containing porous organic polymers using different crosslinkers[J]. Polymer,2016,82:114-120. |
APA | Zhang D,Tao LM,Wang QH,Wang TM,&王廷梅.(2016).A facile synthesis of cost-effective triphenylamine-containing porous organic polymers using different crosslinkers.Polymer,82,114-120. |
MLA | Zhang D,et al."A facile synthesis of cost-effective triphenylamine-containing porous organic polymers using different crosslinkers".Polymer 82(2016):114-120. |
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1-s2.0-S003238611530(1430KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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