Swelling behavior of guar gum-g-poly(sodium acrylate-co-styrene)/attapulgite superabsorbent composites | |
Department | 环境材料与生态化学研究发展中心 |
Shi XN(施小宁); Wang WB(王文波); Wang AQ(王爱勤); 王爱勤 aqwang@licp.cas.cn | |
2011 | |
Source Publication | Journal of Macromolecular Science, Part B: Physics |
ISSN | 0022-2348 |
Volume | 50Issue:10Pages:1847-1863 |
Abstract | A series of superabsorbent composites, guar gum-g-poly(sodium acrylate-costyrene)/attapulgite [GG-g-P(NaA-co-St)/APT], were prepared by simultaneous grafting partially neutralized acrylic acid and hydrophobic styrene (St) onto guar gum in the presence of attapulgite as an inorganic component. Equilibrium swelling capacity strongly depended on the concentration of St, drastically increasing with increasing St concentration to 24.3 mmol/L and then decreasing. The influence of St concentration on the swelling kinetics of the superabsorbent was studied by means of a Schott's second-order model. The proper amount of St is of benefit for the improvement of the initial swelling rate in either distilled water or saline solution. The influence of St concentration on the swelling behaviors in various external media (the aqueous solutions of various salts, pHs, hydrophilic organic solvent/water mixture and surfactants) was also investigated systematically. Results showed that the concentration of St is the key factor influencing equilibrium swelling capacity of the superabsorbent composites in each swelling media, and moderate amounts of St could enhance the responsiveness of the corresponding superabsorbent composite to external stimulation. |
Keyword | Attapulgite Guar Gum Styrene Superabsorbent Composite Swellingbehavior |
Subject Area | 功能高分子 |
Funding Organization | 科技部863项目(2006AA03Z0454,2006AA100215) |
Indexed By | SCI |
Language | 英语 |
Funding Project | 功能复合材料组 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/90 |
Collection | 环境材料与生态化学研究发展中心 |
Corresponding Author | 王爱勤 aqwang@licp.cas.cn |
Recommended Citation GB/T 7714 | Shi XN,Wang WB,Wang AQ,et al. Swelling behavior of guar gum-g-poly(sodium acrylate-co-styrene)/attapulgite superabsorbent composites[J]. Journal of Macromolecular Science, Part B: Physics,2011,50(10):1847-1863. |
APA | 施小宁,王文波,王爱勤,&王爱勤 aqwang@licp.cas.cn.(2011).Swelling behavior of guar gum-g-poly(sodium acrylate-co-styrene)/attapulgite superabsorbent composites.Journal of Macromolecular Science, Part B: Physics,50(10),1847-1863. |
MLA | 施小宁,et al."Swelling behavior of guar gum-g-poly(sodium acrylate-co-styrene)/attapulgite superabsorbent composites".Journal of Macromolecular Science, Part B: Physics 50.10(2011):1847-1863. |
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