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Rapid removal of Pb(II) from aqueous solution by chitosan-g-poly(acrylic acid)/attapulgite/ sodium humate composite hydrogels
Department环境材料与生态化学研究发展中心
Zhang JP(张俊平); Jin YL(金叶玲); Wang AQ(王爱勤); 王爱勤 aqwang@licp.cas.cn
2011
Source PublicationEnvironmental Technology
ISSN0959-3330
Volume32Issue:5Pages:523-531
AbstractA series of novel granular chitosang -poly(acrylic acid)/attapulgite/sodium humate (CTS-g -PAA/APT/SH) composite hydrogels were successfully prepared by one-step free radical graft polymerization and applied as adsorbents for the removal of Pb(II) from aqueous solution. The effects of adsorbent composition (including the contents of APT, SH and CTS) on adsorption capacity and adsorption rate were investigated in detail. Results from kinetic experiments showed that the rate of Pb(II) adsorption on the composite hydrogels was quite fast, that more than 90% of the equilibrium adsorption capacity occurs within two minutes and that the adsorption equilibrium could be achieved within 10 minutes. The adsorption kinetics fit well with the pseudo-second order equation. The introduced SH is helpful for both adsorption capacity and adsorption rate. The -COOH and -COO? of PAA, -NH2 of CTS, Ph-O? and -COO? of SH, as well as cation exchange and Si-OH of APT, participate in adsorption of Pb(II). The synergistic effect of these groups is responsible for the high adsorption capacity and rate.
KeywordComposite Hydrogels Adsorption Pb(Ii) Attapulgite Sodium Humate
Subject Area功能高分子
Funding Organization国家自然科学基金项目(20877077)
Indexed BySCI
Language英语
Funding Project功能复合材料组
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/85
Collection环境材料与生态化学研究发展中心
Corresponding Author王爱勤 aqwang@licp.cas.cn
Recommended Citation
GB/T 7714
Zhang JP,Jin YL,Wang AQ,et al. Rapid removal of Pb(II) from aqueous solution by chitosan-g-poly(acrylic acid)/attapulgite/ sodium humate composite hydrogels[J]. Environmental Technology,2011,32(5):523-531.
APA 张俊平,金叶玲,王爱勤,&王爱勤 aqwang@licp.cas.cn.(2011).Rapid removal of Pb(II) from aqueous solution by chitosan-g-poly(acrylic acid)/attapulgite/ sodium humate composite hydrogels.Environmental Technology,32(5),523-531.
MLA 张俊平,et al."Rapid removal of Pb(II) from aqueous solution by chitosan-g-poly(acrylic acid)/attapulgite/ sodium humate composite hydrogels".Environmental Technology 32.5(2011):523-531.
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