LICP OpenIR  > 固体润滑国家重点实验室(LSL)
Effects of duty cycle and water immersion on the composition and friction performance of diamond-like carbon films prepared by the pulsed-DC plasma technique
Department固体润滑国家重点实验室 ; 先进润滑与防护材料研究发展中心
Zhao F(赵飞); Li HX(李红轩); Ji L(吉利); Mo YF(莫宇飞); Quan WL(权伟龙); Wang YJ(王永军); Chen JM(陈建敏); Zhou HD(周惠娣)
2011
Source PublicationThin Solid Films
ISSN0040-6090
Volume519Pages:2043-2048
AbstractDiamond-like carbon (DLC) films were prepared in a pulsed-DC discharged CH4/Ar plasma. Effects of duty cycle ([ton/(ton+toff)]×100%) on the composition and properties of DLC films were investigated. In general, the increased duty cycle led to an up-shift of the G peak position, an increase in the ID/IG and sp2 /sp3 ratio, and a reduction of the number of C–Hbonds and the filmhardness, revealing a graphitization tendencywith increasing duty cycle. Tribologically, ultralow and steady friction coefficients (0.005 and 0.008) in dry nitrogen atmosphere were obtained for the films prepared under a duty cycle of 50% and 65%. The unique mechanical property and chemical nature brought by the moderate sp2 /sp3 ratio and the proper H content were considered to be responsible as the films deposited in this duty cycle range could simultaneously provide the high chemical inertness and the ultrasmooth sliding surfaces required for achieving ultralow friction. In addition, the structure was less vulnerable towatermolecules in the case of stewing. The diamond-like nature and the ultralowfriction performance were hardly affected even experiencing a 4-month immersion in water.
KeywordDiamond-like Carbon Pulsed Dc Plasma Raman Spectroscopy Infrared Spectroscopy Friction X-ray Photoelectron Spectroscopy
Subject Area材料科学与物理化学
Funding Organizationthe National Natural Science Foundation of China (grant NO.50705093;NO.50575217);the Innovative Group Foundation from NSFC (grant NO.50421502);the National 973 Project (NO.2007 CB607601)
Indexed BySCI
Language英语
Funding Project磨损和表面工程组
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/834
Collection固体润滑国家重点实验室(LSL)
中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心
Corresponding AuthorChen JM(陈建敏)
Recommended Citation
GB/T 7714
Zhao F,Li HX,Ji L,et al. Effects of duty cycle and water immersion on the composition and friction performance of diamond-like carbon films prepared by the pulsed-DC plasma technique[J]. Thin Solid Films,2011,519:2043-2048.
APA 赵飞.,李红轩.,吉利.,莫宇飞.,权伟龙.,...&周惠娣.(2011).Effects of duty cycle and water immersion on the composition and friction performance of diamond-like carbon films prepared by the pulsed-DC plasma technique.Thin Solid Films,519,2043-2048.
MLA 赵飞,et al."Effects of duty cycle and water immersion on the composition and friction performance of diamond-like carbon films prepared by the pulsed-DC plasma technique".Thin Solid Films 519(2011):2043-2048.
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