Effects of duty cycle and water immersion on the composition and friction performance of diamond-like carbon films prepared by the pulsed-DC plasma technique | |
Department | 固体润滑国家重点实验室 ; 先进润滑与防护材料研究发展中心 |
Zhao F(赵飞); Li HX(李红轩); Ji L(吉利); Mo YF(莫宇飞); Quan WL(权伟龙); Wang YJ(王永军); Chen JM(陈建敏); Zhou HD(周惠娣) | |
2011 | |
Source Publication | Thin Solid Films |
ISSN | 0040-6090 |
Volume | 519Pages:2043-2048 |
Abstract | Diamond-like carbon (DLC) films were prepared in a pulsed-DC discharged CH4/Ar plasma. Effects of duty cycle ([ton/(ton+toff)]×100%) on the composition and properties of DLC films were investigated. In general, the increased duty cycle led to an up-shift of the G peak position, an increase in the ID/IG and sp2 /sp3 ratio, and a reduction of the number of C–Hbonds and the filmhardness, revealing a graphitization tendencywith increasing duty cycle. Tribologically, ultralow and steady friction coefficients (0.005 and 0.008) in dry nitrogen atmosphere were obtained for the films prepared under a duty cycle of 50% and 65%. The unique mechanical property and chemical nature brought by the moderate sp2 /sp3 ratio and the proper H content were considered to be responsible as the films deposited in this duty cycle range could simultaneously provide the high chemical inertness and the ultrasmooth sliding surfaces required for achieving ultralow friction. In addition, the structure was less vulnerable towatermolecules in the case of stewing. The diamond-like nature and the ultralowfriction performance were hardly affected even experiencing a 4-month immersion in water. |
Keyword | Diamond-like Carbon Pulsed Dc Plasma Raman Spectroscopy Infrared Spectroscopy Friction X-ray Photoelectron Spectroscopy |
Subject Area | 材料科学与物理化学 |
Funding Organization | the National Natural Science Foundation of China (grant NO.50705093;NO.50575217);the Innovative Group Foundation from NSFC (grant NO.50421502);the National 973 Project (NO.2007 CB607601) |
Indexed By | SCI |
Language | 英语 |
Funding Project | 磨损和表面工程组 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/834 |
Collection | 固体润滑国家重点实验室(LSL) 中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心 |
Corresponding Author | Chen JM(陈建敏) |
Recommended Citation GB/T 7714 | Zhao F,Li HX,Ji L,et al. Effects of duty cycle and water immersion on the composition and friction performance of diamond-like carbon films prepared by the pulsed-DC plasma technique[J]. Thin Solid Films,2011,519:2043-2048. |
APA | 赵飞.,李红轩.,吉利.,莫宇飞.,权伟龙.,...&周惠娣.(2011).Effects of duty cycle and water immersion on the composition and friction performance of diamond-like carbon films prepared by the pulsed-DC plasma technique.Thin Solid Films,519,2043-2048. |
MLA | 赵飞,et al."Effects of duty cycle and water immersion on the composition and friction performance of diamond-like carbon films prepared by the pulsed-DC plasma technique".Thin Solid Films 519(2011):2043-2048. |
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