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Effect of biotite content of hydrogels on enhanced removal of cationic dye from aqueous solution
Department环境材料与生态化学研究发展中心
Liu Y(刘毅); Zheng YA(郑易安); Wang AQ(王爱勤); 王爱勤 aqwang@licp.cas.cn
2011
Source PublicationIonics
ISSN0947-7047
Volume17Issue:6Pages:535-543
AbstractA series of chitosan-g-poly(acrylic acid)/biotite (CTS-g-PAA/BT) hydrogels with unique clay biotite (BT) were prepared and used to remove cationic dye methylene blue (MB) from aqueous solution by batch adsorption experiments. Variables of the system including BT content, initial pH, contact time, initial concentration, and temperature affecting the adsorption efficiency of MB by CTS-g-PAA/BT hydrogels were investigated. Kinetic studies indicated that the adsorption data well followed pseudo second-order kinetics. Langmuir and Freundlich isotherm models were applied to experimental equilibrium data of MB adsorption depending on temperature. The adsorption equilibrium data obeyed Langmuir isotherm, and the monolayer adsorption capacity calculated from the Langmuir isotherm was 2,125.70 mg/g for CTS-g-PAA/10% BT at 30 °C. The adsorption capacity was much higher compared with other hydrogels with the same content of other clays. The introduction of BT into the hydrogel could effectively improve its adsorption properties and reduce the cost. Thermodynamic parameters were evaluated for the dye-adsorbent systems and revealed that the adsorption process was spontaneous and exothermic in nature. All the information gave an indication that CTS-g-PAA/10% BT could potentially be applied as an efficient adsorbent for cationic dye removal from aqueous solution.
KeywordHydrogel Biotite Methylene Blue Adsorption Equilibrium Kinetics
Subject Area功能高分子
Funding Organization国家自然科学基金项目(20877077)
Indexed BySCI
Language英语
Funding Project功能复合材料组
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/79
Collection环境材料与生态化学研究发展中心
Corresponding Author王爱勤 aqwang@licp.cas.cn
Recommended Citation
GB/T 7714
Liu Y,Zheng YA,Wang AQ,et al. Effect of biotite content of hydrogels on enhanced removal of cationic dye from aqueous solution[J]. Ionics,2011,17(6):535-543.
APA 刘毅,郑易安,王爱勤,&王爱勤 aqwang@licp.cas.cn.(2011).Effect of biotite content of hydrogels on enhanced removal of cationic dye from aqueous solution.Ionics,17(6),535-543.
MLA 刘毅,et al."Effect of biotite content of hydrogels on enhanced removal of cationic dye from aqueous solution".Ionics 17.6(2011):535-543.
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