LICP OpenIR  > 固体润滑国家重点实验室(LSL)
Self-assembly fibrillar network gels of simple surfactants in organic solvents
Department固体润滑国家重点实验室
Wang D(王栋); Hao JC(郝京诚)
2011
Source PublicationLangmuir
ISSN0743-7463
Volume27Issue:5Pages:1713-1717
AbstractThe self-assembled fibrillar network (SAFIN) organogels of a simple surfactant molecule, sodium laurate (C11H23COONa, SL), in organic solvents were investigated. The sol-gel transformation temperature depended on the SL concentration, the solvent, and the concentration ofNaþ was evaluated.An important finding is thatNaþ ions play an important role in forming organogels, which was regarded as the induction factor of gelation, but other cations, for instance, Li þ,Kþ, Ca2þ, and Mg2þ, do not have this capability. The observations by transmission electron microscopy (TEM) and scanning electron microscopy (SEM) proved that the organogels were network structures with fibers and ribbons by trapping a certain amount of organic solvent.High-resolution TEM(HR-TEM) images indicated that each of the fibers or ribbons was composed of cylindrical micelles. The X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectra demonstrated that SL molecules in gels behave similarly to those in SL crystals. The mechanism of organogel formation was elaborated to provide a better understanding of fibrous surfactant gels in organic solvents.
Subject Area材料科学与物理化学
Funding Organizationthe NSFC (grant NO.20625307 & 21033005);the National Basic Research Program of China (973 Program;2009CB930103);NFS of Shandong Province (Z2008B01)
Indexed BySCI
Language英语
Citation statistics
Cited Times:37[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/780
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorHao JC(郝京诚)
Recommended Citation
GB/T 7714
Wang D,Hao JC. Self-assembly fibrillar network gels of simple surfactants in organic solvents[J]. Langmuir,2011,27(5):1713-1717.
APA 王栋,&郝京诚.(2011).Self-assembly fibrillar network gels of simple surfactants in organic solvents.Langmuir,27(5),1713-1717.
MLA 王栋,et al."Self-assembly fibrillar network gels of simple surfactants in organic solvents".Langmuir 27.5(2011):1713-1717.
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