Research on some aromatic schiff base compounds and metal complexes with different substituted groups | |
Department | 固体润滑国家重点实验室 |
Jiao TF(焦体峰); Liu J(刘建); Gao LH(高丽华); Zhou JX(周靖欣); Xing YY(邢媛媛) | |
2011 | |
Source Publication | Key Engineering Materials |
ISSN | 1662-9795 |
Volume | 474-476Pages:1523-1528 |
Abstract | Two aromatic Schiff base derivatives and the corresponding metal complexes with different substituted groups were synthesized and characterized by many methods. The products were characterized by UV-Vis spectra, FT-IR spectra and thermal analysis, while the thermal stability was measured by TG-DTA instrument. FT-IR analysis indicated that the nitrogen atom in imino group and oxygen atom in phenolic hydroxyl group participated in coordinating with transition metal ion in different bridged mode. UV spectra also verified that different coordination modes can be performed between metal ions and ligands. In addition, the thermal stability of metal complexes had been obviously superior to that of the ligands. All results give a useful clue to obtain Schiff base derivatives with versatile property by regulating intramolecular substituted group and species of metal ion. The present results have showed potential application in fields of functional material and catalyst. |
Keyword | Schiff Base Metal Complex Ligand Substituted Groups Thermal Stability |
Subject Area | 材料科学与物理化学 |
Funding Organization | the National Natural Science Foundation of China (NO.20903078);the Natural Science Foundation of Hebei Province (NO.B2009000347);Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (NO.CPRC020);the Open Foundation of State Key Laboratory of Solid Lubrication (Lanzhou Institute of Chemical Physics;CAS) (NO.1002);the Scientific Research Plan of Education Department of Hebei Province (NO.Z2009146);the Scientific;Technological Research and Development Program of Qinhuangdao City (Nos. 201001A100;201001A101);the Doctoral Foundation of Yanshan University (NO.B360) |
Indexed By | SCI |
Language | 英语 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/775 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Jiao TF(焦体峰) |
Recommended Citation GB/T 7714 | Jiao TF,Liu J,Gao LH,et al. Research on some aromatic schiff base compounds and metal complexes with different substituted groups[J]. Key Engineering Materials,2011,474-476:1523-1528. |
APA | 焦体峰,刘建,高丽华,周靖欣,&邢媛媛.(2011).Research on some aromatic schiff base compounds and metal complexes with different substituted groups.Key Engineering Materials,474-476,1523-1528. |
MLA | 焦体峰,et al."Research on some aromatic schiff base compounds and metal complexes with different substituted groups".Key Engineering Materials 474-476(2011):1523-1528. |
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