| Spectral and thermal investigation of novel glycine-based schiff base derivative and its metal complexes | |
| Department | 固体润滑国家重点实验室 |
| Jiao TF(焦体峰); Zhou Y(周媛); Zhou JX(周靖欣); Xing YY(邢媛媛); Li YH(李阳辉) | |
| 2011 | |
| Source Publication | Key Engineering Materials
 |
| ISSN | 1662-9795 |
| Volume | 474-476Pages:543-547 |
| Abstract | A novel glycine-based Schiff base derivative (abbreviated as C16GlySb) containing long alkyl chain was synthesized from glycine reacted with 4-cetyloxy-2-hydroxybenzaldehyde and sequentially coordinated with various metal ions to give the corresponding metal complexes (abbreviated as G-M). The products were characterized by UV-Vis spectra and FT-IR spectra. At the same time, the thermal stability was measured by TG-DTA instrument. FT-IR analysis indicated that the nitrogen atom in imino group, oxygen atom in phenolic hydroxyl group, and carboxylic ion participated in coordinating with transition metal ion in doubly-bridged mode. UV spectra showed that compared with ethanol solution, the cast film on quartz plate showed H-type or J-type aggregate structure. In addition, the thermal stability of G-M had been obviously superior to that of the ligand C16GlySb. The present results have showed potential application in fields of functional material and catalyst. |
| Keyword | Glyscine Schiff Base Metal Complex Ligand Thermal Stability |
| Subject Area | 材料科学与物理化学 |
| Funding Organization | the National Natural Science Foundation of China (NO.20903078);the Natural Science Foundation of Hebei Province (NO.B2009000347);Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (NO.CPRC020);the Open Foundation of State Key Laboratory of Solid Lubrication (Lanzhou Institute of Chemical Physics;CAS) (NO.1002);the Scientific Research Plan of Education Department of Hebei Province (NO.Z2009146);the Scientific and Technological Research and Development Program of Qinhuangdao City (Nos. 201001A100;201001A101);the Doctoral Foundation of Yanshan University (NO.B360) |
| Indexed By | SCI |
| Language | 英语 |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/774 |
| Collection | 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Jiao TF(焦体峰) |
| Recommended Citation GB/T 7714 | Jiao TF,Zhou Y,Zhou JX,et al. Spectral and thermal investigation of novel glycine-based schiff base derivative and its metal complexes[J]. Key Engineering Materials,2011,474-476:543-547. |
| APA | 焦体峰,周媛,周靖欣,邢媛媛,&李阳辉.(2011).Spectral and thermal investigation of novel glycine-based schiff base derivative and its metal complexes.Key Engineering Materials,474-476,543-547. |
| MLA | 焦体峰,et al."Spectral and thermal investigation of novel glycine-based schiff base derivative and its metal complexes".Key Engineering Materials 474-476(2011):543-547. |
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| File Name/Size | DocType | Version | Access | License | ||
| 2011543-547.PDF（2061KB） | 开放获取 | License | View Application Full Text | |||
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