Design and investigation of novel L-glutamate-based Schiff base compounds with different substituted groups | |
Department | 固体润滑国家重点实验室 |
Jiao TF(焦体峰); Liu J(刘建); Zhou JX(周靖欣); Li XH(李旭辉); Xing YY(邢媛媛) | |
2011 | |
Source Publication | Key Engineering Materials |
ISSN | 1662-9795 |
Volume | 474-476Pages:1529-1533 |
Abstract | Some novel L-glutamate-based Schiff base compounds with glutamate segment and different substituted groups have been designed and synthesized from the reaction of aromatic L-glutamate amine with different aldehydes. It has been found that depending on the molecular structures and substituted groups, the formed Schiff base compounds showed different properties, indicating distinct regulation of molecular design. UV and IR data confirmed commonly the formation of Schiff base as well as aromatic substituted groups in molecular structures. Thermal analysis also clarified the structural influence of these compounds in different temperature ranges. The difference of thermal stability is mainly attributed to molecular structures, formation of Schiff base group and different substituted groups. These results indicated that the the special properties of Schiff base compounds could be regulated through the design of molecular structures and substituted groups, which leads to potential application in fields of functional material as well as catalyst. |
Keyword | Schiff Base Glutamate Functional Material Substituted Groups Spectral Measurement Thermal Analysis |
Subject Area | 材料科学与物理化学 |
Funding Organization | the National Natural Science Foundation of China (NO.20903078);the Natural Science Foundation of Hebei Province (NO.B2009000347);Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (NO.CPRC020);the Open Foundation of State Key Laboratory of Solid Lubrication (Lanzhou Institute of Chemical Physics;CAS)(NO.1002);the Scientific Research Plan of Education Department of Hebei Province (NO.Z2009146);the Scientific and Technological Research and Development Program of Qinhuangdao City (Nos. 201001A100;201001A101);the Doctoral Foundation of Yanshan University (NO.B360) |
Indexed By | SCI |
Language | 英语 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/772 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Jiao TF(焦体峰) |
Recommended Citation GB/T 7714 | Jiao TF,Liu J,Zhou JX,et al. Design and investigation of novel L-glutamate-based Schiff base compounds with different substituted groups[J]. Key Engineering Materials,2011,474-476:1529-1533. |
APA | 焦体峰,刘建,周靖欣,李旭辉,&邢媛媛.(2011).Design and investigation of novel L-glutamate-based Schiff base compounds with different substituted groups.Key Engineering Materials,474-476,1529-1533. |
MLA | 焦体峰,et al."Design and investigation of novel L-glutamate-based Schiff base compounds with different substituted groups".Key Engineering Materials 474-476(2011):1529-1533. |
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