LICP OpenIR  > 非现建制
新型烯烃氢甲酰化催化剂的合成及其催化作用
Department非现建制
赵继全; 罗玉忠; 傅宏祥
1995
Source Publication精细石油化工
ISSN1003-9384
Issue1Pages:49-52
Abstract用膦化的交联聚氯乙烯与YCCo3(CO)9(Y=Ph, Cl, H及—C3H7)制备了A, B, C, D四个担载羰基钻原子簇催化剂。利用红外光谱、紫外漫反射光谱鉴定了它们的结构。在4.0 MPa(CO:H2=1:1)条件下, 考察了它们对烯烃氢甲酰反应的催化作用。实验表明,该原子簇催化剂以A和B的活性低, C和D活性高。当温度140 ℃, 反应23 h, 用D作催化剂, 1-庚烯的转化率达97.4%, 选择性93.4%。
Keyword膦化聚氯乙烯 甲川型九羰基三钴 羰基钴 氢甲酰化 1-庚烯 Phosphino-pvc Methylidynetricobalt Nonacarbonyl Cobalt Carbonyl Hydroformylation 1-heptene
Subject Area物理化学
Language中文
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/7430
Collection非现建制
Recommended Citation
GB/T 7714
赵继全,罗玉忠,傅宏祥. 新型烯烃氢甲酰化催化剂的合成及其催化作用[J]. 精细石油化工,1995(1):49-52.
APA 赵继全,罗玉忠,&傅宏祥.(1995).新型烯烃氢甲酰化催化剂的合成及其催化作用.精细石油化工(1),49-52.
MLA 赵继全,et al."新型烯烃氢甲酰化催化剂的合成及其催化作用".精细石油化工 .1(1995):49-52.
Files in This Item:
File Name/Size DocType Version Access License
新型烯烃氢甲酰化催化剂的合成及其催化作用(256KB) 开放获取CC BY-NC-SAView Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[赵继全]'s Articles
[罗玉忠]'s Articles
[傅宏祥]'s Articles
Baidu academic
Similar articles in Baidu academic
[赵继全]'s Articles
[罗玉忠]'s Articles
[傅宏祥]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[赵继全]'s Articles
[罗玉忠]'s Articles
[傅宏祥]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: 新型烯烃氢甲酰化催化剂的合成及其催化作用_赵继全.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.