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羰基三核钌簇Ru3(CO)9(C6H5)2N2HCS的合成和晶体结构
Department非现建制
徐吉春; 焦凤英; 殷元骐; 黄幼青; 胡盛志
1994
Source Publication结构化学
ISSN0254-5861
Volume13Issue:3Pages:239-242
Abstract本文根道了Ru3(CO)9(C6H5)2N2HCS的合成及晶体结构,晶体属单斜晶系,空间群P21/m,晶胞参数a=9.604(2),b=14.279(5),c=9.986(1)Å,β=103.45(1)°,V=1331.9 Å,Mr=782.61,Z=2,Dx=1.951 g/cm3,μ(MoKa)=17.73 cm-1,F(000)=754,R=0.038.(C6H5)2N2HCS通过N和S原子与3个钌原子成螯合配位,另外还有九个羰基与之配位。整个分子具有CS对称性。
Keyword三核羰基簇 金属有机化合物 晶体结构 Trinuclear Carbonyl Cluster Metal Organic Compound Crystal Structure
Subject Area物理化学
Funding Organization国家自然科学基金;中国科学院上海有机所金属有机开放室、结构化学国家重点实验室资助
Language中文
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/7332
Collection非现建制
Recommended Citation
GB/T 7714
徐吉春,焦凤英,殷元骐,等. 羰基三核钌簇Ru3(CO)9(C6H5)2N2HCS的合成和晶体结构[J]. 结构化学,1994,13(3):239-242.
APA 徐吉春,焦凤英,殷元骐,黄幼青,&胡盛志.(1994).羰基三核钌簇Ru3(CO)9(C6H5)2N2HCS的合成和晶体结构.结构化学,13(3),239-242.
MLA 徐吉春,et al."羰基三核钌簇Ru3(CO)9(C6H5)2N2HCS的合成和晶体结构".结构化学 13.3(1994):239-242.
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