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庚烯配位的羰基钌氢簇合物H3Ru3(CO)9[C7H11]的合成及晶体结构
Department非现建制
梁丽君; 罗玉忠; 郁开北
1994
Source Publication化学学报
ISSN0567-7351
Issue2Pages:160-165
Abstract本文合成了庚烯配位的羰基钌氢簇合物H3Ru3(CO)9(C7H11),用IR、NMR、MS和元素分析等手段对此簇合物进行了结构表征,推测其为含有金属-氢键的羰基钌簇合物,并且庚烯的双键被打开,X射线衍射测定进一步肯定了上述结论。 簇合物为三斜晶系,空间群为PI 晶胞参数: a=0.9726(2)nm,b=0.9868(1)nm,c=1.1104(2)nm,α=103.22(1)°,β=89.89(1)°,γ=91.55(1)°,V =1.0370(3)nm3,Z=2, μ=21.59cm-1, Dσ=2.09g/cm3, F(000)=628,最终偏差因子R=0.0371。
Keyword羰基钌簇合物 合成 晶体结构
Subject Area物理化学
Language中文
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/7331
Collection非现建制
Corresponding Author梁丽君
Recommended Citation
GB/T 7714
梁丽君,罗玉忠,郁开北. 庚烯配位的羰基钌氢簇合物H3Ru3(CO)9[C7H11]的合成及晶体结构[J]. 化学学报,1994(2):160-165.
APA 梁丽君,罗玉忠,&郁开北.(1994).庚烯配位的羰基钌氢簇合物H3Ru3(CO)9[C7H11]的合成及晶体结构.化学学报(2),160-165.
MLA 梁丽君,et al."庚烯配位的羰基钌氢簇合物H3Ru3(CO)9[C7H11]的合成及晶体结构".化学学报 .2(1994):160-165.
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