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轻稀土硝酸盐与TDD 2∶2配合物的合成及结构
Department非现建制
刘伟生; 谭民裕; 郁开北; 谭干祖
1994
Source Publication中国科学:化学
ISSN1674-7224
Volume24Issue:4Pages:362-370
Abstract本文合成并表征了轻稀土硝酸盐与N,N,N′,N′-四苯基-3,6-二氧撑辛二酰胺(TDD)的2:2型配合物:[RE(TDD)2(H2O)2][RE(NO3)6]1—4(1:RE=La; 2:RE=Ce; 3:RE=Pr; 4:RE=Nd)和[Ce(TDD)2(H2O)2][Ce(NO3)6]•CH3OH•2H2O 5.5的单晶结构分析表明, TDD作为四齿配体与Ce离子形成半环状配位结构, 两个TDD的构象稍有差异。配阳、阴离子中Ce的配位数分别为10和12, 配位多面体分别为二帽变形反四棱柱和变形二十面体。
Keyword轻稀土 开链冠醚 2:2配合物
Subject Area无机化学
Funding Organization国家自然科学基金;国家教委高等院校博士点基金;国家科委“攀登计划”(稀土科学基础研究)资助课题
Language中文
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/7315
Collection非现建制
Corresponding Author谭民裕
Recommended Citation
GB/T 7714
刘伟生,谭民裕,郁开北,等. 轻稀土硝酸盐与TDD 2∶2配合物的合成及结构[J]. 中国科学:化学,1994,24(4):362-370.
APA 刘伟生,谭民裕,郁开北,&谭干祖.(1994).轻稀土硝酸盐与TDD 2∶2配合物的合成及结构.中国科学:化学,24(4),362-370.
MLA 刘伟生,et al."轻稀土硝酸盐与TDD 2∶2配合物的合成及结构".中国科学:化学 24.4(1994):362-370.
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