| Spherical beta-cyclodextrin-silica hybrid materials for multifunctional chiral stationary phases | |
| Department | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Wang LT(王利涛)1,2 ; Dong SQ(董树清)1,2; Han F(韩峰)1,2; Zhao YW(赵应伟)1,2; Zhang X(张霞)1,2; Zhang XL(张晓莉)1,2,3; Qiu HD(邱洪灯)1,2; Zhao L(赵亮)1,2; Zhao L(赵亮)
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| 2015 | |
| Source Publication | Journal of Chromatography A
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| ISSN | 0021-9673 |
| Volume | 1383Pages:70-78 |
| Abstract | Spherical β-CD-silica hybrid materials have been prepared successfully by simple one-pot polymerization, which provide a new strategy to construct new type of HPLC chiral stationary phases. Various β-CD, ethane, triazinyl and 3,5-dimethylphenyl functional groups that can provide multiple interactions were introduced into the pore channels and pore wall framework of mesoporous materials, respectively. The materials towards some chiral, acidic, anilines and phenols compounds showed multiple chromato-graphic separation functions including racemic resolution, anion exchange and a chiral separations with a typical feature of normal/reversed phase chromatography. Multi-tasking including racemic resolution and a chiral separations for selected compounds were performed simultaneously on a chiral chJournal of Chromatography Aromatographic column. The multifunctional character of materials arises from the multiple interactions including hydrophobic interaction, π–π interaction, anion exchange, inclusion interaction and hydrogen bonding interaction. |
| Keyword | Hybrid Materials Cyclodextrins Multifunctional Separations Chiral Resolution Liquid Chromatography |
| Subject Area | 分析化学与药物化学 |
| DOI | 10.1016/j.chroma.2015.01.023 |
| Funding Organization | the National Natural Science Foundation of China (Nos. 21405162;21405161;21275150;20675085);the Personnel Training Project of the West Light Foundation of the Chinese Academy of Sciences (2012, to Litao Wang) |
| Indexed By | SCI |
| If | 3.926 |
| Language | 英语 |
| Funding Project | 药物手性分离研究组;药物分离材料研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/7165 |
| Collection | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
| Corresponding Author | Zhao L(赵亮) |
| Affiliation | 1.Chinese Acad Sci, Key Lab Nat Med Gansu Prov, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Nat Med Gansu Prov, Lanzhou 730000, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| Recommended Citation GB/T 7714 | Wang LT,Dong SQ,Han F,et al. Spherical beta-cyclodextrin-silica hybrid materials for multifunctional chiral stationary phases[J]. Journal of Chromatography A,2015,1383:70-78. |
| APA | Wang LT.,Dong SQ.,Han F.,Zhao YW.,Zhang X.,...&赵亮.(2015).Spherical beta-cyclodextrin-silica hybrid materials for multifunctional chiral stationary phases.Journal of Chromatography A,1383,70-78. |
| MLA | Wang LT,et al."Spherical beta-cyclodextrin-silica hybrid materials for multifunctional chiral stationary phases".Journal of Chromatography A 1383(2015):70-78. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 1-s2.0-S002196731500（2294KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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