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Engineering the field emission properties of graphene film by gas adsorbates
Department清洁能源化学与材料实验室
Li J(李军)1,3,4; Yan XB(阎兴斌)1; Gou GY(苟高阳)2; Wang Z(王昭)2; Chen JT(陈江涛)1; Yan XB(阎兴斌); Gou GY(苟高阳)
2014
Source PublicationPhysical Chemistry Chemical Physics
ISSN1463-9076
Volume16Issue:5Pages:1850-1855
AbstractWe study the effect of different gas adsorbates (N2, O2, and CO2) on the field emission (FE) properties of graphene film. Our experimental measurements show that, except for N2, adsorption of O2 and CO2 reduces the FE current of the graphene film. Moreover, the measured FE hysteresis loop is almost quenched after adsorbing O2 or CO2. The ab initio calculations quantify the experimental results by predicting a larger work function and smaller FE current for the graphene system after O2 or CO2 adsorption. In contrast, the change of FE properties in N2 adsorbed graphene is negligible. A ‘‘depolarization electric field model’’ is then proposed to explain the observed FE hysteresis behavior.
Subject Area材料科学与物理化学
DOI10.1039/c3cp53106f
Funding Organizationthe Ministry of Science and Technology of China through a 973-Project under (Grant No. 2012CB619401;2012CB619402);the Natural Science Foundation of China (51002161;11204230;11204228); the Top Hundred Talents Program of Chinese Academy of Sciences;The National Supercomputer Center in Tianjin (NSCC)
Indexed BySCI
If4.493
Language英语
Funding Project低维材料与化学储能课题组
compositor第一作者单位
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Cited Times:17[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/7137
Collection清洁能源化学与材料实验室
Corresponding AuthorYan XB(阎兴斌); Gou GY(苟高阳)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lab Clean Energy Chem & Mat, Lanzhou 730000, Peoples R China
2.Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, Xian 710049, Peoples R China
3.Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China
4.Chinese Acad Sci, Grad Univ, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Li J,Yan XB,Gou GY,et al. Engineering the field emission properties of graphene film by gas adsorbates[J]. Physical Chemistry Chemical Physics,2014,16(5):1850-1855.
APA Li J.,Yan XB.,Gou GY.,Wang Z.,Chen JT.,...&苟高阳.(2014).Engineering the field emission properties of graphene film by gas adsorbates.Physical Chemistry Chemical Physics,16(5),1850-1855.
MLA Li J,et al."Engineering the field emission properties of graphene film by gas adsorbates".Physical Chemistry Chemical Physics 16.5(2014):1850-1855.
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