Engineering the field emission properties of graphene film by gas adsorbates | |
Department | 清洁能源化学与材料实验室 |
Li J(李军)1,3,4; Yan XB(阎兴斌)1; Gou GY(苟高阳)2; Wang Z(王昭)2; Chen JT(陈江涛)1; Yan XB(阎兴斌); Gou GY(苟高阳) | |
2014 | |
Source Publication | Physical Chemistry Chemical Physics |
ISSN | 1463-9076 |
Volume | 16Issue:5Pages:1850-1855 |
Abstract | We study the effect of different gas adsorbates (N2, O2, and CO2) on the field emission (FE) properties of graphene film. Our experimental measurements show that, except for N2, adsorption of O2 and CO2 reduces the FE current of the graphene film. Moreover, the measured FE hysteresis loop is almost quenched after adsorbing O2 or CO2. The ab initio calculations quantify the experimental results by predicting a larger work function and smaller FE current for the graphene system after O2 or CO2 adsorption. In contrast, the change of FE properties in N2 adsorbed graphene is negligible. A ‘‘depolarization electric field model’’ is then proposed to explain the observed FE hysteresis behavior. |
Subject Area | 材料科学与物理化学 |
DOI | 10.1039/c3cp53106f |
Funding Organization | the Ministry of Science and Technology of China through a 973-Project under (Grant No. 2012CB619401;2012CB619402);the Natural Science Foundation of China (51002161;11204230;11204228); the Top Hundred Talents Program of Chinese Academy of Sciences;The National Supercomputer Center in Tianjin (NSCC) |
Indexed By | SCI |
If | 4.493 |
Language | 英语 |
Funding Project | 低维材料与化学储能课题组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/7137 |
Collection | 清洁能源化学与材料实验室 |
Corresponding Author | Yan XB(阎兴斌); Gou GY(苟高阳) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lab Clean Energy Chem & Mat, Lanzhou 730000, Peoples R China 2.Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, Xian 710049, Peoples R China 3.Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Grad Univ, Beijing 100080, Peoples R China |
Recommended Citation GB/T 7714 | Li J,Yan XB,Gou GY,et al. Engineering the field emission properties of graphene film by gas adsorbates[J]. Physical Chemistry Chemical Physics,2014,16(5):1850-1855. |
APA | Li J.,Yan XB.,Gou GY.,Wang Z.,Chen JT.,...&苟高阳.(2014).Engineering the field emission properties of graphene film by gas adsorbates.Physical Chemistry Chemical Physics,16(5),1850-1855. |
MLA | Li J,et al."Engineering the field emission properties of graphene film by gas adsorbates".Physical Chemistry Chemical Physics 16.5(2014):1850-1855. |
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12.pdf(1982KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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