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N-Methylation of amine and nitro compounds with CO2/H-2 catalyzed by Pd/CuZrOx under mild reaction conditions
Department绿色化学研究发展中心
Cui XJ(崔新江); Zhang Y(张妍); Deng YQ(邓友全); Shi F(石峰); Shi F(石峰)
The second departmentosso国家重点实验室
2014
Source PublicationChemical Communications
ISSN1359-7345
Volume50Issue:88Pages:13521-13524
AbstractAn active Pd/ZrCuOx catalyst was prepared for the reductive amination of CO2. The N-methylation of amines and nitro compounds with CO2/H2 can be realized with up to 97% yield under relatively mild reaction conditions. N-Formylation becomes the main reaction if the reaction was performed under milder conditions or using Pd/ZnZrOx as the catalyst.
Subject Area物理化学与绿色催化
DOI10.1039/c4cc05119j
Indexed BySCI
If6.834
Language英语
Funding Project纳米催化课题组;绿色催化课题组
compositor第一作者单位
Citation statistics
Cited Times:103[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/7112
Collection绿色化学研究发展中心
羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding AuthorShi F(石峰)
AffiliationChinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Cui XJ,Zhang Y,Deng YQ,et al. N-Methylation of amine and nitro compounds with CO2/H-2 catalyzed by Pd/CuZrOx under mild reaction conditions[J]. Chemical Communications,2014,50(88):13521-13524.
APA Cui XJ,Zhang Y,Deng YQ,Shi F,&石峰.(2014).N-Methylation of amine and nitro compounds with CO2/H-2 catalyzed by Pd/CuZrOx under mild reaction conditions.Chemical Communications,50(88),13521-13524.
MLA Cui XJ,et al."N-Methylation of amine and nitro compounds with CO2/H-2 catalyzed by Pd/CuZrOx under mild reaction conditions".Chemical Communications 50.88(2014):13521-13524.
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