Synthesis and Properties of Low-surface-energy Polyimides | |
Department | 固体润滑国家重点实验室 |
Wang HZ(王海忠); Ye Q(叶谦); Wang XL(王晓龙); Wang XL(王晓龙) | |
2014 | |
Source Publication | Chemistry Letters |
ISSN | 0366-7022 |
Volume | 43Issue:12Pages:1926-1928 |
Abstract | An aromatic diamine monomer, 1H,1H-perfluorooctyl 3,5-diaminobenzoate (PFD), was synthesized in three steps, which was used to prepare the polyimides containing pendant perfluoroalkyl chains via the polymerization of PFD with commercial 4,4′-(hexafluoroisopropylidene)diphthalic anhydride. Various characterization techniques including thermogravimetric analysis, infrared spectroscopy, and X-ray photoelectron spectroscopy were used to characterize the new polyimides with perfluoroalkyl chains. The resulting polyimide film exhibits hydrophobicity with a contact angle of 95° for water, and the calculated surface free energy is 37.4 mNm-1. Superhydrophobic surfaces were also demonstrated by coating the polyimide containing pendant perfluorooctyl chains on rough alumina substrate. |
Subject Area | 材料科学与物理化学 |
DOI | 10.1246/cl.140825 |
Funding Organization | Key Project of National Nature Science Foundation of China (No. 21204095);the National Natural Science Foundation of China (No. 51171202) |
Indexed By | SCI |
If | 1.230 |
Language | 英语 |
Funding Project | 空间润滑材料组;材料表面与界面行为研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/7105 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Wang XL(王晓龙) |
Affiliation | Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Wang HZ,Ye Q,Wang XL,et al. Synthesis and Properties of Low-surface-energy Polyimides[J]. Chemistry Letters,2014,43(12):1926-1928. |
APA | Wang HZ,Ye Q,Wang XL,&王晓龙.(2014).Synthesis and Properties of Low-surface-energy Polyimides.Chemistry Letters,43(12),1926-1928. |
MLA | Wang HZ,et al."Synthesis and Properties of Low-surface-energy Polyimides".Chemistry Letters 43.12(2014):1926-1928. |
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F_43_1926.pdf(2251KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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