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Thermoreversible Gel Lubricants through Universal Supramolecular Assembly of a Nonionic Surfactant in a Variety of Base Lubricating Liquids
Department固体润滑国家重点实验室
Yu QL(于强亮)1,2; Fan MJ(凡明锦)1; Li DM(李冬梅)1; Song ZH(宋增红)1,2; Cai MR(蔡美荣)1; Zhou F(周峰)1; Liu WM(刘维民)1; Cai MR(蔡美荣); Zhou F(周峰); Liu WM(刘维民)
2014
Source PublicationACS Applied Materials and Interfaces
ISSN1944-8244
Volume6Issue:18Pages:15783-15794
AbstractThe present paper investigates a new type of thermoreversible gel lubricant obtained by supramolecular assembly of low-molecular-weight organic gelator (LMWG) in different base oils. The LMWG is a nonionic surfactant with polar headgroup and hydrophobic tail that can self-assemble through collective noncovalent intermolecular interactions (Hbonding, hydrophobic interaction) to form fibrous structures and trap base oils (mineral oils, synthetic oils, and water) in the as-formed cavities. The gel lubricants are fully thermoreversible upon heating-up and cooling down and exhibit thixotropic characteristics. This makes them semisolid lubricants, but they behave like oils. The tribological test results disclosed that the LMWG could also effectively reduce friction and wear of sliding pairs compared with base oils without gelator. It is expected that when being used in oil-lubricated components, such as gear, rolling bearing, and so on, gel lubricant may effectively avoid base oil leak and evaporation loss and so is a benefit to operation and lubrication failure for a long time.
KeywordGel Lubricant Supramolecular Assembly Thermoreversible Lubrication Wear
Subject Area材料科学与物理化学
DOI10.1021/am502832z
Funding Organizationthe NSFC (21173243;51305428;51105354);“‘973’” program (2013CB632301);West Light Foundation of The Chinese Academy of Sciences
Indexed BySCI
If6.723
Language英语
Funding Project材料表面与界面行为研究组;空间润滑材料组
compositor第一作者单位
Citation statistics
Cited Times:65[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/6860
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorCai MR(蔡美荣); Zhou F(周峰); Liu WM(刘维民)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Yu QL,Fan MJ,Li DM,et al. Thermoreversible Gel Lubricants through Universal Supramolecular Assembly of a Nonionic Surfactant in a Variety of Base Lubricating Liquids[J]. ACS Applied Materials and Interfaces,2014,6(18):15783-15794.
APA Yu QL.,Fan MJ.,Li DM.,Song ZH.,Cai MR.,...&刘维民.(2014).Thermoreversible Gel Lubricants through Universal Supramolecular Assembly of a Nonionic Surfactant in a Variety of Base Lubricating Liquids.ACS Applied Materials and Interfaces,6(18),15783-15794.
MLA Yu QL,et al."Thermoreversible Gel Lubricants through Universal Supramolecular Assembly of a Nonionic Surfactant in a Variety of Base Lubricating Liquids".ACS Applied Materials and Interfaces 6.18(2014):15783-15794.
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