| Aryl-palladium-NHC complex: efficient phosphine-free catalyst precursors for the carbonylation of aryl iodides with amines or alkynes | |
| Department | OSSO国家重点实验室 |
Zhang CY(张春艳)1,2 ; Liu JH(刘建华)1; Xia CG(夏春谷)1; Liu JH(刘建华); Xia CG(夏春谷)
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| 2014 | |
| Source Publication | Organic & Biomolecular Chemistry
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| ISSN | 1477-0520 |
| Volume | 12Issue:47Pages:9702-9706 |
| Abstract | A series of aryl-palladium-NHC compounds was prepared according to the reported methods and their catalytic activity in the carbonylation of aryl iodides to synthesize alpha-keto amides and alkynones was examined. These practical aryl-palladium-NHC complexes have shown highly efficient catalyzed carbonylation and Sonogashira carbonylation reactions, with high turnover number in synthesis of alpha-keto amides (TON = 4300) and in synthesis of alkynones (TON = 980). |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c4ob01878h |
| Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21373248;21133011;21073209) |
| Indexed By | SCI |
| If | 3.562 |
| Language | 英语 |
| Funding Project | 均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/6814 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Liu JH(刘建华); Xia CG(夏春谷) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang CY,Liu JH,Xia CG,et al. Aryl-palladium-NHC complex: efficient phosphine-free catalyst precursors for the carbonylation of aryl iodides with amines or alkynes[J]. Organic & Biomolecular Chemistry,2014,12(47):9702-9706. |
| APA | Zhang CY,Liu JH,Xia CG,刘建华,&夏春谷.(2014).Aryl-palladium-NHC complex: efficient phosphine-free catalyst precursors for the carbonylation of aryl iodides with amines or alkynes.Organic & Biomolecular Chemistry,12(47),9702-9706. |
| MLA | Zhang CY,et al."Aryl-palladium-NHC complex: efficient phosphine-free catalyst precursors for the carbonylation of aryl iodides with amines or alkynes".Organic & Biomolecular Chemistry 12.47(2014):9702-9706. |
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| File Name/Size | DocType | Version | Access | License | ||
| Aryl-palladium-NHC c（237KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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