One-pot synthesis of mesoporous ZrPW solid acid catalyst for liquid phase benzylation of anisole | |
Department | OSSO国家重点实验室 |
Miao ZC(苗智超)1,2; Song HL(宋焕玲)1,3; Zhao HH(赵华华)1; Xu LL(徐磊磊)1,2; Chou LJ(丑凌军)1,3; Chou LJ(丑凌军) | |
2014 | |
Source Publication | Catalysis Science & Technology |
ISSN | 2044-4753 |
Volume | 4Issue:3Pages:838-850 |
Abstract | Mesoporous zirconium phosphotungstate (M-ZrPW), with large specific surface area (~170 m2 g−1), large pore volume (~0.25 cm3 g−1), uniform pore size distribution (~6.5 nm) and tunable W/Zr ratios (0–0.2), was successfully prepared via a facile one-pot evaporation-induced self-assembly (EISA) strategy. Smallangle X-ray diffraction (SXRD), transmission electron microscopy (TEM) and scanning electron microscopy (SEM) characterizations showed that these materials had a mesoporous structure even when the W/Zr ratio reached up to 0.2. The tungsten species introduced via this strategy highly were dispersed among the wall of mesoporous framework. More importantly, the tungsten species greatly improved the Brønsted acidic property and catalytic activity in the Friedel–Crafts benzylation reaction. The highest activity was obtained at a W/Zr ratio of 0.2 with the strongest Brønsted acidity. In addition, the influences of various reaction parameters such as reaction time, amount of catalyst and calcination temperature of the catalyst, systematically investigated in this paper. Furthermore, the M-ZrPW showed a higher catalytic activity than H-Beta, H-ZSM5 and ZrPW prepared by the sol–gel method. Meanwhile, M-ZrPW could be reused at least for five cycles in the benzylation reaction without any notable decrease of catalytic activity. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1039/c3cy00918a |
Funding Organization | the National Basic Research Program of PR China (No. 2011CB201404);the National Natural Science Foundation of China (no. 21133011) |
Indexed By | SCI |
If | 5.426 |
Language | 英语 |
Funding Project | 多相选择氧化课题组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/6723 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Chou LJ(丑凌军) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Suzhou 215123, Peoples R China |
Recommended Citation GB/T 7714 | Miao ZC,Song HL,Zhao HH,et al. One-pot synthesis of mesoporous ZrPW solid acid catalyst for liquid phase benzylation of anisole[J]. Catalysis Science & Technology,2014,4(3):838-850. |
APA | Miao ZC,Song HL,Zhao HH,Xu LL,Chou LJ,&丑凌军.(2014).One-pot synthesis of mesoporous ZrPW solid acid catalyst for liquid phase benzylation of anisole.Catalysis Science & Technology,4(3),838-850. |
MLA | Miao ZC,et al."One-pot synthesis of mesoporous ZrPW solid acid catalyst for liquid phase benzylation of anisole".Catalysis Science & Technology 4.3(2014):838-850. |
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