| Phosphine-Free, Efficient Double Carbonylation of Aryl Iodides with Amines Catalyzed by Water-Insoluble and Water-Soluble N-Heterocyclic Carbene-Amine Palladium Complexes | |
| Department | 清洁能源化学与材料实验室 |
Wang Y(汪妍)1; Yang XL(杨晓龙)2 ; Zhang CY(张春艳)2; Yu JQ(于健强)1; Liu JH(刘建华)2; Xia CG(夏春谷)2; Yu JQ(于健强); Liu JH(刘建华)
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| The second department | osso国家重点实验室 |
| 2014 | |
| Source Publication | Advanced Synthesis & Catalysis
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| ISSN | 1615-4150 |
| Volume | 356Issue:11-12Pages:2539-2546 |
| Abstract | The water-insoluble and water-soluble Nheterocyclic carbene (NHC)–amine palladium complexes, Ipr-Pd(deba)Cl and SO3-Ipr-Pd(deba)Cl, were synthesized. Both catalysts exhibit excellent activity in the phosphine-free double carbonylation of aryl iodides with amines to produce a-keto amides. Moreover, as the water-soluble catalyst exhibits significant compatibility in the aqueous phase with the activities of different Pd-NHC complexes, we conclude that the intramolecular amine ligand strongly affects the selectivity of the products in double carbonylation reaction and serves as an alternative of phosphine ligands. |
| Keyword | Double Carbonylation N-heterocyclic Carbene-amine Palladium Complexes Phosphine-free Reaction Water-soluble Complexes |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/adsc.201400040 |
| Funding Organization | the National Natural Science Foundation of China (No. 21073209;No. 21373248;No. 21133011) |
| Indexed By | SCI |
| If | 5.663 |
| Language | 英语 |
| Funding Project | 光催化与醇醚燃料研究组;均相催化课题组;羰基金属功能材料课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/6524 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 清洁能源化学与材料实验室 |
| Corresponding Author | Yu JQ(于健强); Liu JH(刘建华) |
| Affiliation | 1.Chinese Acad Sci, Lab Clean Energy Chem & Mat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Wang Y,Yang XL,Zhang CY,et al. Phosphine-Free, Efficient Double Carbonylation of Aryl Iodides with Amines Catalyzed by Water-Insoluble and Water-Soluble N-Heterocyclic Carbene-Amine Palladium Complexes[J]. Advanced Synthesis & Catalysis,2014,356(11-12):2539-2546. |
| APA | Wang Y.,Yang XL.,Zhang CY.,Yu JQ.,Liu JH.,...&刘建华.(2014).Phosphine-Free, Efficient Double Carbonylation of Aryl Iodides with Amines Catalyzed by Water-Insoluble and Water-Soluble N-Heterocyclic Carbene-Amine Palladium Complexes.Advanced Synthesis & Catalysis,356(11-12),2539-2546. |
| MLA | Wang Y,et al."Phosphine-Free, Efficient Double Carbonylation of Aryl Iodides with Amines Catalyzed by Water-Insoluble and Water-Soluble N-Heterocyclic Carbene-Amine Palladium Complexes".Advanced Synthesis & Catalysis 356.11-12(2014):2539-2546. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 汪妍--2014.pdf（252KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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