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担载三核羰基钴簇的合成、表征和烯烃氢甲酰化反应
Department非现建制
沈海邑; 罗玉忠; 傅宏祥; 马玉源; 高兰云
1992
Source Publication分子催化
ISSN1001-3555
Volume6Issue:2Pages:128-135
Abstract通过配体交换反应合成了膦化硅胶担载的羰基钴簇配合物(Si)—PPh2[BrCCo3(CO)9-2], 用IR、XPS和DPS对其结构进行了表征, 并测得了担载簇配合物的金属含量, 研究了担载簇(Si)—PPh2[BrCCo3(CO)9-2]在烯烃氢甲酰化反应中的催化活性. 结果表明, 担载的三核羰基钴簇可达到与均相三核钴簇基本一致的反应活性, 在一定的反应条件下, 烯烃转化率和醇醛收率均在85%以上, 有很少量的加氢产物生成。
Keyword担载催化剂 金属簇 氢甲酰化 烯烃 Supported Catalyst Cluster Hydroformylation Olefin
Subject Area物理化学
Funding Organization国家自然科学基金资助项目
Language中文
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/6449
Collection非现建制
Corresponding Author罗玉忠
Recommended Citation
GB/T 7714
沈海邑,罗玉忠,傅宏祥,等. 担载三核羰基钴簇的合成、表征和烯烃氢甲酰化反应[J]. 分子催化,1992,6(2):128-135.
APA 沈海邑,罗玉忠,傅宏祥,马玉源,&高兰云.(1992).担载三核羰基钴簇的合成、表征和烯烃氢甲酰化反应.分子催化,6(2),128-135.
MLA 沈海邑,et al."担载三核羰基钴簇的合成、表征和烯烃氢甲酰化反应".分子催化 6.2(1992):128-135.
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