| Metal-Free and Recyclable Route to Synthesize Polysubstituted Olefins via C-C Bond Construction from Direct Dehydrative Coupling of Alcohols or Alkenes with Alcohols Catalyzed by Sulfonic Acid-Functionalized Ionic Liquids | |
| Department | OSSO国家重点实验室 |
Han F(韩峰) ; Yang L(杨磊); Li Z(李臻); Zhao YW(赵应伟); Xia CG(夏春谷); Yang L(杨磊); Xia CG(夏春谷)
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| 2014 | |
| Source Publication | Advanced Synthesis & Catalysis
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| ISSN | 1615-4150 |
| Volume | 356Issue:11-12Pages:2506-2516 |
| Abstract | A direct synthesis of polysubstituted olefins via construction of C-C bonds, which involves the direct dehydrative coupling of alcohols or alkenes with alcohols, was realized using a series of alkanesulfonic acid group-functionalized ionic liquids (SO3H-functionlization ILs) without additives. The metal-free and recyclable catalyst system avoided the disposal and neutralization of acidic catalysts after reaction and tolerated a broad range of substrates, including benzylic, allyl, propargylic, aliphatic and aromatic or aliphatic olefins. Additionally, the catalytic system was suitable for a gram-scale preparation. Preliminary mechanistic studies indicated that the C-H bond cleavage in this reaction might be involved in the rate-determining step. |
| Keyword | Alcohols Alkenes C-c Bond Construction Direct Dehydrative Coupling Sulfonic Acid-functionalized Ionic Liquids |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/adsc.201301150 |
| Funding Organization | the National Science Foundation of China (No. 21303231;21173241;21133011);the National Basic Research Program of China (2011CB201404);the Chinese Academy of Sciences |
| Indexed By | SCI |
| If | 5.663 |
| Language | 英语 |
| Funding Project | 均相催化课题组;有机功能材料研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/6184 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Yang L(杨磊); Xia CG(夏春谷) |
| Affiliation | Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Han F,Yang L,Li Z,et al. Metal-Free and Recyclable Route to Synthesize Polysubstituted Olefins via C-C Bond Construction from Direct Dehydrative Coupling of Alcohols or Alkenes with Alcohols Catalyzed by Sulfonic Acid-Functionalized Ionic Liquids[J]. Advanced Synthesis & Catalysis,2014,356(11-12):2506-2516. |
| APA | Han F.,Yang L.,Li Z.,Zhao YW.,Xia CG.,...&夏春谷.(2014).Metal-Free and Recyclable Route to Synthesize Polysubstituted Olefins via C-C Bond Construction from Direct Dehydrative Coupling of Alcohols or Alkenes with Alcohols Catalyzed by Sulfonic Acid-Functionalized Ionic Liquids.Advanced Synthesis & Catalysis,356(11-12),2506-2516. |
| MLA | Han F,et al."Metal-Free and Recyclable Route to Synthesize Polysubstituted Olefins via C-C Bond Construction from Direct Dehydrative Coupling of Alcohols or Alkenes with Alcohols Catalyzed by Sulfonic Acid-Functionalized Ionic Liquids".Advanced Synthesis & Catalysis 356.11-12(2014):2506-2516. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Metal-Free and Recyc（381KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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