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膦取代的羰基铂簇的合成、结构和性质
Department非现建制
翟纬绪; 赵转云
1986
Source Publication有机化学
ISSN0253-2786
Issue2Pages:134-138
AbstractPt(PPh3)2Cl2在碱性介质中, 与一氧化碳直接进行还原及羰基化反应, 得到五种膦取代的羰基铂配合物: Pt5(μ2-CO)5(CO)(PPh3)4 1, Pt3(μ2-CO)3(PPh3)3 2, Pt3(μ2-CO)3(PPh3)4 3, Pt4(μ2-CO)5(PPh3)4 4, 以及Pt(Cl)(PPh3)2(COOCH3) 5。经X-射线单晶衍射分析, 确定了新的三核铂羰基簇2以及配合物5的分子结构。还讨论了1和5的生成机理。
Keyword三苯基膦 羰基配合物 铂配合物 簇形化合物 Triphenylphosphine Carbonyl Complex Platinum Complex Cluster Compound
Subject Area物理化学
Language中文
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/6062
Collection非现建制
Recommended Citation
GB/T 7714
翟纬绪,赵转云. 膦取代的羰基铂簇的合成、结构和性质[J]. 有机化学,1986(2):134-138.
APA 翟纬绪,&赵转云.(1986).膦取代的羰基铂簇的合成、结构和性质.有机化学(2),134-138.
MLA 翟纬绪,et al."膦取代的羰基铂簇的合成、结构和性质".有机化学 .2(1986):134-138.
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