| Trinuclear Metal Cluster Complexes Containing Fischer-Type Carbene Group from Oxidative Addition Reactions of Tris(N,N-diethyldithiocarbamato)cobalt with Co2(CO)8 and Ru3(CO)12 | |
| Department | 羰基合成与选择氧化国家重点实验室 |
Yang JM(杨晶沐); Hu B(胡斌) ; Xia CG(夏春谷)
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| 2008 | |
| Source Publication | Journal of Cluster Science
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| ISSN | 1040-7278 |
| Volume | 19Pages:615-621 |
| Abstract | Two new Fischer-type carbene-containing trinuclear transition-metal clusters: (l3-S)Co3(CO)7[l, g2-SCNEt2] 1 and CoRu2(CO)9[l3, g2-SCNEt2] 2 were obtained by the reaction of tris(N,N-diethyldithiocarbamato)cobalt with Co2(CO)8 and Ru3(CO)12. These clusters contain thiocarboxamido ligand in different coordination modes. The thiocarboxamido ligand served as monometalated or dimetalated sulfur(diethy1amino) carbene ligand in these clusters. Clusters 1 and 2 were characterized by IR, 1H NMR, and single-crystal X-ray diffraction. |
| Keyword | Trinuclear Metal Cluster Fischer-type Carbene Thiocarboxamido Ligand Crystal Structure |
| Subject Area | 清洁催化与生物转化 |
| Funding Organization | the National Science Fund for Distinguished Young Scholars of China (No. 20625308) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 清洁催化与生物转化研究组 ; 羰基金属功能材料研究组 |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/600 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xia CG(夏春谷) |
| Recommended Citation GB/T 7714 | Yang JM,Hu B,Xia CG. Trinuclear Metal Cluster Complexes Containing Fischer-Type Carbene Group from Oxidative Addition Reactions of Tris(N,N-diethyldithiocarbamato)cobalt with Co2(CO)8 and Ru3(CO)12[J]. Journal of Cluster Science,2008,19:615-621. |
| APA | 杨晶沐,胡斌,&夏春谷.(2008).Trinuclear Metal Cluster Complexes Containing Fischer-Type Carbene Group from Oxidative Addition Reactions of Tris(N,N-diethyldithiocarbamato)cobalt with Co2(CO)8 and Ru3(CO)12.Journal of Cluster Science,19,615-621. |
| MLA | 杨晶沐,et al."Trinuclear Metal Cluster Complexes Containing Fischer-Type Carbene Group from Oxidative Addition Reactions of Tris(N,N-diethyldithiocarbamato)cobalt with Co2(CO)8 and Ru3(CO)12".Journal of Cluster Science 19(2008):615-621. |
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| B49_J.Clust.Sci.,200（262KB） | 开放获取 | License | View Application Full Text | |||
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