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王冠高聚物担载四核钴羰基簇催化剂的醛化反应活性
Department非现建制
杨佩仪; 傅宏祥; 罗玉忠
1984
Source Publication有机化学
ISSN0253-2786
Issue2Pages:107-110
Abstract本文用二苯并-18-冠-6高聚物作因相化载体,通过化学健合, 合成了担载的四核钴羰基簇催化剂Crown-Co4, 并对该催化剂进行了元素分析、红外光谱及X射线光电子能谱(XPS)等方面的测试分析; 还考察了不同温度、不同极性溶剂及不同类型烯烃对醛化活性的影响。实验证明, 该催化剂对直链端位烯烃的醛化活性高于均相的苯基-四核钴羰基簇催化利Ph-Co4。二苯并-18-冠-6高聚物载体能明显改善催化性能。
Keyword冠醚 簇状化合物 载体 钴络合物 羰基络合物 催化剂 制备 醛化 Crown Ether Compound Cluster Compound Support Cobalt Complex Carbonyl Complex Catalyst Preparation Hydroformylation
Subject Area物理化学
Language中文
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/5965
Collection非现建制
Recommended Citation
GB/T 7714
杨佩仪,傅宏祥,罗玉忠. 王冠高聚物担载四核钴羰基簇催化剂的醛化反应活性[J]. 有机化学,1984(2):107-110.
APA 杨佩仪,傅宏祥,&罗玉忠.(1984).王冠高聚物担载四核钴羰基簇催化剂的醛化反应活性.有机化学(2),107-110.
MLA 杨佩仪,et al."王冠高聚物担载四核钴羰基簇催化剂的醛化反应活性".有机化学 .2(1984):107-110.
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