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Ti(Ⅲ)/TEOA/K2PtCl6复合催化体系的光解水制氢的研究
Department非现建制
王在玺; 李树本; 何云陔; 高福; 易淑云; 郑新华; 缪德埙; 陈英武
1982
Source Publication催化学报
ISSN0253-9837
Volume3Issue:1Pages:21-27
Abstract本文报道了用紫外光激发Ti(Ⅲ)/TEOA/K2PtCl6复合催化体系分解水产生氢气的试验结果。其中, TiCl3是起始光活性物质。组分浓度, 光照时间和体系的pH对产氢速度均有一定影响。含0.1毫克分子TiCl3, 0.15毫克分子2,2′-bpy,4毫克分子TEOA和0.025毫克分子K2PtCl6, pH为7.5的50毫升中性水溶液, 其最大产氢速度为1.01毫升/时。光照30小时, 放氢速度基本不变。可能的光催化机理是Ti3+首先被光激发为*Ti3+, 进而被TEOA还原得到TEOA+和Ti2+, Ti2+在铂的催化作用下同H+反应产生H2气, 同时又复原为Ti3+
Subject Area物理化学
Language中文
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/5838
Collection非现建制
Recommended Citation
GB/T 7714
王在玺,李树本,何云陔,等. Ti(Ⅲ)/TEOA/K2PtCl6复合催化体系的光解水制氢的研究[J]. 催化学报,1982,3(1):21-27.
APA 王在玺.,李树本.,何云陔.,高福.,易淑云.,...&陈英武.(1982).Ti(Ⅲ)/TEOA/K2PtCl6复合催化体系的光解水制氢的研究.催化学报,3(1),21-27.
MLA 王在玺,et al."Ti(Ⅲ)/TEOA/K2PtCl6复合催化体系的光解水制氢的研究".催化学报 3.1(1982):21-27.
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