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金属簇络合物YCCo3(CO)9的合成与醛化性能的研究
Department非现建制
傅宏祥; 罗玉忠; 杨震宇; 王云普; 武楠; 张爱民; 蔡恩(王户)
1980
Source Publication催化学报
ISSN0253-9837
Volume1Issue:4Pages:281-290
Abstract本文提出一种常压下由硝酸钴和三卤化物经相转移催化合成钴簇络合物YCCo3(CO)9的新方法, 并用该法合成了HCCo3(CO)9, ClCCo3(CO)9, PhCCo3(CO)9和EtOOCCo3(CO)9等四种络合物。考察了这些络合物对己烯的酸化活性和PhCCo3(CO)9对各种烯烃醛化时结构与活性的关系, 以及它们的异构化和加氢活性。实验结果表明它们是一类在较缓和条件下具有较高活性和选择性的醛化催化剂。当反应温度130 ℃和压力40 公斤/厘米2时, 己烯转化率达90%以上, 选择性在80%以上。
Subject Area物理化学
Language中文
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/5783
Collection非现建制
Recommended Citation
GB/T 7714
傅宏祥,罗玉忠,杨震宇,等. 金属簇络合物YCCo3(CO)9的合成与醛化性能的研究[J]. 催化学报,1980,1(4):281-290.
APA 傅宏祥.,罗玉忠.,杨震宇.,王云普.,武楠.,...&蔡恩.(1980).金属簇络合物YCCo3(CO)9的合成与醛化性能的研究.催化学报,1(4),281-290.
MLA 傅宏祥,et al."金属簇络合物YCCo3(CO)9的合成与醛化性能的研究".催化学报 1.4(1980):281-290.
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