| BISMUTH-MOLYBDATE CATALYST FOR THE OXIDATIVE DEHYDROGENATION OF n-BUTENES | |
| Department | 非现建制 |
| 中国科学院兰州化学物理研究所 | |
| 1979 | |
| Source Publication | 中国科学 数学(英文版)
 |
| ISSN | 1674-7283 |
| Volume | 12Issue:4Pages:431-440 |
| Abstract | The results of a study of some factors in the preparation of bismuth-molybdate catalyst for the oxidative dehydrogenation of n-butenes is presented briefly in this paper. Kinetic investigation of the relevant reactions over co-gelled and impregnated catalysts suggests that the conversion of butenes and butadiene could be treated as the first order reactions. The complex reactions occurring in the oxidative dehydrogenation of butenes could be adapted into a framework of a simplified reaction scheme, and the kinetic parameters were evaluated for each step in the framework. The physicochemical and catalytic properties of fresh catalyst were investigated and compared with those of deactivated catalyst from commercial reactor, as well as those of specially treated catalysts from a simulated laboratory run in order to have an insight into the cause of catalyst deactivation. A speculation about the nature of active site and reaction mechanism on the catalyst is proposed. |
| Subject Area | 物理化学 |
| Language | 英语 |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/5780 |
| Collection | 非现建制 |
| Recommended Citation GB/T 7714 | 中国科学院兰州化学物理研究所. BISMUTH-MOLYBDATE CATALYST FOR THE OXIDATIVE DEHYDROGENATION OF n-BUTENES[J]. 中国科学 数学(英文版),1979,12(4):431-440. |
| APA | 中国科学院兰州化学物理研究所.(1979).BISMUTH-MOLYBDATE CATALYST FOR THE OXIDATIVE DEHYDROGENATION OF n-BUTENES.中国科学 数学(英文版),12(4),431-440. |
| MLA | 中国科学院兰州化学物理研究所."BISMUTH-MOLYBDATE CATALYST FOR THE OXIDATIVE DEHYDROGENATION OF n-BUTENES".中国科学 数学(英文版) 12.4(1979):431-440. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| BISMUTH_MOLYBDAT_省略_（487KB） | 开放获取 | CC BY-NC-SA | View Application Full Text | |||
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