| Reaction of (Carbonyl)triruthenium with Acetylferrocene Thiosemicarbazone: Synthesis, X-ray Diffraction, and Insight into the Solution Structures | |
| Department | 羰基合成与选择氧化国家重点实验室 |
Yang JM(杨晶沐); Hu B(胡斌) ; Hu XX(胡霄雪); Xia CG(夏春谷)
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| 2008 | |
| Source Publication | European Journal of Inorganic Chemistry
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| ISSN | 1434-1948 |
| Pages | 5617-5621 |
| Abstract | Reaction of acetylferrocene thiosemicarbazone [L] with Ru3(CO)12 was investigated. Two new complexes, Ru3(CO)9-[L-H] (1) and Ru2(CO)4[L]2 (2) were isolated. They were characterized by IR, 1H NMR, and 13C NMR spectroscopic analysis. The crystal structures of 1 and 2 were also determined. In trinuclear cluster 1, the acetylferrocene thiosemicarbazone ligand was deprotonated and acted as an N,S-chelating ligand as well as a sulfur bridge. Dinuclear compound 2 is the first bis(cycloruthenated acetylferrocene thiosemicarbazone) carbonyl derivative. This complex contains two ruthenium atoms in a dinuclear structure with a Cferrocene, N, S2, and (CO)2 coordination sphere for each ruthenium atom, as both L ligands act as a Cferrocene, N, S2 chelate, and sulfur bridge. The behavior of 1 and 2 under electrospray ionization mass spectrometry (ESI-MS) was studied and the key intermediate Ru(CO)2[L-H] (3) in the formation of 2 was directly detected in the reaction solution. |
| Keyword | Ruthenium Carbonyl Ligands Multinuclear Compounds Structure Elucidation |
| Subject Area | 清洁催化与生物转化 |
| Funding Organization | the National Science Fund for Distinguished Young Scholars of China (No. 20625308) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 羰基金属功能材料研究组 ; 清洁催化与生物转化研究组 ; 管理与大型仪器组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/563 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xia CG(夏春谷) |
| Recommended Citation GB/T 7714 | Yang JM,Hu B,Hu XX,et al. Reaction of (Carbonyl)triruthenium with Acetylferrocene Thiosemicarbazone: Synthesis, X-ray Diffraction, and Insight into the Solution Structures[J]. European Journal of Inorganic Chemistry,2008:5617-5621. |
| APA | 杨晶沐,胡斌,胡霄雪,&夏春谷.(2008).Reaction of (Carbonyl)triruthenium with Acetylferrocene Thiosemicarbazone: Synthesis, X-ray Diffraction, and Insight into the Solution Structures.European Journal of Inorganic Chemistry,5617-5621. |
| MLA | 杨晶沐,et al."Reaction of (Carbonyl)triruthenium with Acetylferrocene Thiosemicarbazone: Synthesis, X-ray Diffraction, and Insight into the Solution Structures".European Journal of Inorganic Chemistry (2008):5617-5621. |
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| B15_Eur.J.Inorg.Chem（411KB） | 开放获取 | License | View Application Full Text | |||
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