| Magnetic hydroxyapatite-encapsulated gamma-Fe2O3 nanoparticles functionalized with basic ionic liquids for aqueous Knoevenagel condensation | |
| Department | 羰基合成与选择氧化国家重点实验室 |
Zhang Y(张妍); Xia CG(夏春谷)
| |
| 2009 | |
| Source Publication | Applied Catalysis A: General
 |
| ISSN | 0926-860X |
| Volume | 366Pages:141-147 |
| Abstract | Hydroxyapatite-encapsulated g-Fe2O3 nanoparticles functionalized with diethyl aliphatic amine basic ionic liquids were synthesized and used as efficient magnetic catalysts for aqueous Knoevenagel condensation reactions. Quantitative conversion of the reactants was achieved under mild conditions; recycle of the catalyst, through convenient magnetic decantation, shows non-significant loss in activity. In comparison with the controlled experiments catalyzed by homogeneous basic ionic liquids and the basic ionic liquid-modified polystyrene resin, the excellent performance of the magnetic catalyst was attributed to the cooperativity between the base sites generated by framework HAP and the supported basic ionic liquids. |
| Keyword | Magnetic Separation Basic Ionic Liquids Knoevenagel Condensation Cooperativity |
| Subject Area | 清洁催化与生物转化 |
| Funding Organization | the National Natural Sciences Foundation of China (20373082;20625308;20533080) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 清洁催化与生物转化研究组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/554 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xia CG(夏春谷) |
| Recommended Citation GB/T 7714 | Zhang Y,Xia CG. Magnetic hydroxyapatite-encapsulated gamma-Fe2O3 nanoparticles functionalized with basic ionic liquids for aqueous Knoevenagel condensation[J]. Applied Catalysis A: General,2009,366:141-147. |
| APA | 张妍,&夏春谷.(2009).Magnetic hydroxyapatite-encapsulated gamma-Fe2O3 nanoparticles functionalized with basic ionic liquids for aqueous Knoevenagel condensation.Applied Catalysis A: General,366,141-147. |
| MLA | 张妍,et al."Magnetic hydroxyapatite-encapsulated gamma-Fe2O3 nanoparticles functionalized with basic ionic liquids for aqueous Knoevenagel condensation".Applied Catalysis A: General 366(2009):141-147. |
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| 37_Appl.Catal.A-Gen.（465KB） | 开放获取 | License | View Application Full Text | |||
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