| An Efficient Synthesis of Chiral Diamines with Rigid Backbones: Application in Enantioselective Michael Addition of Malonates to Nitroalkenes | |
| Department | 羰基合成与选择氧化国家重点实验室 |
Zhu QM(朱其明); Huang HM(黄汉民) ; Shi DJ(史登健); Shen ZQ(沈志强); Xia CG(夏春谷)
| |
| 2009 | |
| Source Publication | Organic Letters
 |
| ISSN | 1523-7060 |
| Volume | 11Issue:20Pages:4536-4539 |
| Abstract | A new and efficient route for synthesis of enantiomerically pure biisoindoline and its isomer based on the diaza-Cope rearrangement reaction with chiral 1,2-bis(2-hydroxylphenyl)-1,2-diaminoethane as starting material has been developed. The newly prepared biisoindoline was employed as a chiral ligand in the Ni(II)-catalyzed enantioselective Michael addition of malonates to conjugated nitroalkenes, and good to excellent enantioselectivities were obtained. |
| Subject Area | 清洁催化与生物转化 |
| Funding Organization | the National Natural Science Foundation of China (20802085;20625308) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 清洁催化与生物转化研究组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/528 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Huang HM(黄汉民); Xia CG(夏春谷) |
| Recommended Citation GB/T 7714 | Zhu QM,Huang HM,Shi DJ,et al. An Efficient Synthesis of Chiral Diamines with Rigid Backbones: Application in Enantioselective Michael Addition of Malonates to Nitroalkenes[J]. Organic Letters,2009,11(20):4536-4539. |
| APA | 朱其明,黄汉民,史登健,沈志强,&夏春谷.(2009).An Efficient Synthesis of Chiral Diamines with Rigid Backbones: Application in Enantioselective Michael Addition of Malonates to Nitroalkenes.Organic Letters,11(20),4536-4539. |
| MLA | 朱其明,et al."An Efficient Synthesis of Chiral Diamines with Rigid Backbones: Application in Enantioselective Michael Addition of Malonates to Nitroalkenes".Organic Letters 11.20(2009):4536-4539. |
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| 11_Org.Lett.,2009,11（496KB） | 开放获取 | License | View Application Full Text | |||
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