二吡咯甲烷与醌的电荷转移相互作用研究
Department中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室
郭勇; 徐健; 邵士俊
2006-07
Conference Name中国化学会第二十五届学术年会
Source Publication中国化学会第二十五届学术年会论文摘要集(上册)
Funding Organization中国化学会
Pages64
Conference Date2006-07
Conference Place中国吉林长春
Abstract随着理论研究的不断深入和在实践中的广泛应用积累,近年来对电荷转移配合物的研究己深入光敏材料、超导材料、特殊高分子材料及药理学、生物学和材料科学等领域,己引起了各方面专家的极大兴趣和深入开发。通过对二吡咯甲烷与醌类化合物紫外可见光谱、质谱、红外光谱和能谱的定性试验研究表明,二吡咯甲烷作为π电子给予体能够给出电子,醌由于缺电子能够接受电子,两者通过电子转移形成电荷转移配合物。
Other AbstractA colorimetric recognition system, formed by the dipyrromethanes and quinone in solution through non-covalent stacking interaction, has been explored切UV Vis spectroscopy method. The dipyrromethane-quinone molecular complexes were characterized by IR, FAB-MS, XPS pattern, etc.The present results indicated that the dipyrromethanes could serve as electron donors to form colored charge-transfer complexes with tetracyanoquinodimethane (TCNQ).
Keyword二吡咯甲烷 电荷转移配合物
Subject Area分析化学与药物化学
Funding Project药物分子识别研究组
Language中文
Document Type会议论文
Identifierhttp://ir.licp.cn/handle/362003/5076
Collection中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室
Corresponding Author郭勇
Recommended Citation
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郭勇,徐健,邵士俊. 二吡咯甲烷与醌的电荷转移相互作用研究[C],2006:64.
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