| Probing the Characteristics of Mono- or Bimetallic (Iron or Cobalt) Complexes Bearing 2,4-Bis(6-iminopyridin-2-yl)-3H-benzazepines: Synthesis, Characterization, and Ethylene Reactivity | |
| Department | OSSO国家重点实验室 |
| Sun WH(孙文华)1,2,3; Xing QF(邢其锋)1,2; Yu JG(余建刚)1,2; Novikova, Elena1,2; Zhao WZ(赵炜珍)1,2; Tang, Xiubo1,2; Liang TL(梁同玲)1,2; Redshaws, Carl4; Sun WH(孙文华); Carl Redshaw | |
| 2013 | |
| Source Publication | Organometallics
 |
| ISSN | 0276-7333 |
| Volume | 32Issue:8Pages:2309-2318 |
| Abstract | A series of 2,4-bis(6-iminopyridin-2-yl)-3H-benzazepines and the mono- or bimetallic (Fe2+ or Co2+) complexes thereof were synthesized and characterized. All title complexes, when activated by MAO or MMAO, exhibited high activities of up to 4.0 × 107 g (mol of Fe)−1 h−1 for ethylene oligomerization and polymerization. The iron(II) precatalysts generally showed higher activities and produced a wider distribution of products (including oligomers and polyethylene) than did their corresponding cobalt(II) analogues. The bimetallic precatalysts exhibited higher (almost twice) activities in comparison to their monometallic analogues. The distribution of the resulting oligomers closely resembled the Schultz−Flory rule. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/om301086p |
| Funding Organization | NSFC No. 20904059;MOST 863 program No. 2009AA033601 |
| Indexed By | SCI |
| If | 4.253 |
| Language | 英语 |
| compositor | 第三作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/5014 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Sun WH(孙文华); Carl Redshaw |
| Affiliation | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 4.Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England |
| Recommended Citation GB/T 7714 | Sun WH,Xing QF,Yu JG,et al. Probing the Characteristics of Mono- or Bimetallic (Iron or Cobalt) Complexes Bearing 2,4-Bis(6-iminopyridin-2-yl)-3H-benzazepines: Synthesis, Characterization, and Ethylene Reactivity[J]. Organometallics,2013,32(8):2309-2318. |
| APA | Sun WH.,Xing QF.,Yu JG.,Novikova, Elena.,Zhao WZ.,...&Carl Redshaw.(2013).Probing the Characteristics of Mono- or Bimetallic (Iron or Cobalt) Complexes Bearing 2,4-Bis(6-iminopyridin-2-yl)-3H-benzazepines: Synthesis, Characterization, and Ethylene Reactivity.Organometallics,32(8),2309-2318. |
| MLA | Sun WH,et al."Probing the Characteristics of Mono- or Bimetallic (Iron or Cobalt) Complexes Bearing 2,4-Bis(6-iminopyridin-2-yl)-3H-benzazepines: Synthesis, Characterization, and Ethylene Reactivity".Organometallics 32.8(2013):2309-2318. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Organometallics, 201（448KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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