| Study of K/Mn-MgO Supported Fe Catalysts with Fe(CO)(5) and Fe(NO3)(3) as Precursors for CO Hydrogenation to Light Alkenes | |
| Department | OSSO国家重点实验室 |
Tang LP(唐立平)1,2 ; Song CL(宋承立)1; Li ML(李孟丽)1,2; Yang XL(杨晓龙)1; Hu B(胡斌)1; Hu B(胡斌); Yang XL(杨晓龙)
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| 2013 | |
| Source Publication | Chinese Journal of Chemistry
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| ISSN | 1001-604X |
| Volume | 31Issue:10Pages:1263-1268 |
| Abstract | Two K/Mn-MgO supported catalysts were prepared by Fe(CO)5 and Fe(NO3)3 as precursor respectively. The obtained Fe-K/Mn-MgO catalysts were tested for CO hydrogenation to light alkenes and characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectra (XPS), H2 temperature-programmed reduction (H2-TPR), H2, CO and CO2 temperature-programmed desorption (H2, CO/CO2-TPD) and transmission electron microscope (TEM). The results indicated that the catalyst with 10 wt% Fe loading prepared by Fe(CO)5 as precursor showed better performance in syngas to light alkenes than ones obtained from Fe(NO3)3 as precursor, where the CO conversion was 62.50% and the selectivity was 55.95% at 350 ℃, 1.5 MPa and 1000 h−1, respectively. |
| Keyword | Iron Precursor Light Alkenes Co Conversion Selectivity |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/cjoc.201300514 |
| Indexed By | SCI |
| If | 1.040 |
| Language | 英语 |
| Funding Project | 羰基金属功能材料课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/5004 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Hu B(胡斌); Yang XL(杨晓龙) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synthsis & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Tang LP,Song CL,Li ML,et al. Study of K/Mn-MgO Supported Fe Catalysts with Fe(CO)(5) and Fe(NO3)(3) as Precursors for CO Hydrogenation to Light Alkenes[J]. Chinese Journal of Chemistry,2013,31(10):1263-1268. |
| APA | Tang LP.,Song CL.,Li ML.,Yang XL.,Hu B.,...&杨晓龙.(2013).Study of K/Mn-MgO Supported Fe Catalysts with Fe(CO)(5) and Fe(NO3)(3) as Precursors for CO Hydrogenation to Light Alkenes.Chinese Journal of Chemistry,31(10),1263-1268. |
| MLA | Tang LP,et al."Study of K/Mn-MgO Supported Fe Catalysts with Fe(CO)(5) and Fe(NO3)(3) as Precursors for CO Hydrogenation to Light Alkenes".Chinese Journal of Chemistry 31.10(2013):1263-1268. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Chin. J. Chem.pdf（1738KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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