| Oxidative Synthesis of 1,2,4-Triazoles via Heterogeneous Cu-Zn/Al-Ti-Catalyzed Cyclization | |
| Department | ERC国家工程研究中心 |
Meng X(孟旭) ; Zhao PQ(赵培庆)
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| The second department | osso国家重点实验室 |
| 2013 | |
| Conference Name | 第十三届全国均相催化学术会议 |
| Funding Organization | 中国化学会催化委员会均相催化专业委员会主办，中国科学院兰州化学物理研究所承办 |
| Conference Date | 2013-09-25～2013-09-28 |
| Conference Place | 中国苏州 |
| Abstract | A simple and inexpensive heterogeneous catalyst CuOx-ZnO/Al-Ti was successfully employed into cyclized synthesis of 1,2,4-triazoles. This is the first time to synthesize 1,2,4-triazoles between benzonitrile and 2-aminopyridine using oxidative catalytic heterogeneous conditions and eventually the yield is enhanced to 83%. Additionally, the optimizing experiments show using 2 mol% catalyst and cheap air as green oxidant at relative high reaction temperature can bring about the best reaction results. The work about expanding the scope of the reaction under the optimized conditions and examining the reused ability of the heterogeneous catalyst is going on. |
| Subject Area | 物理化学与绿色催化 |
| Indexed By | 其他 |
| Funding Project | 催化新工艺研究组 |
| Language | 英语 |
| Document Type | 会议论文 |
| Identifier | http://ir.licp.cn/handle/362003/4913 |
| Collection | 精细石油化工中间体国家工程研究中心（ERC） 羰基合成与选择氧化国家重点实验室（OSSO） |
| Recommended Citation GB/T 7714 | Meng X,Zhao PQ. Oxidative Synthesis of 1,2,4-Triazoles via Heterogeneous Cu-Zn/Al-Ti-Catalyzed Cyclization[C],2013. |
| Files in This Item: | Download All | |||||
| File Name/Size | DocType | Version | Access | License | ||
| Abstract from Dr.pdf（45KB） | 开放获取 | CC BY-NC-SA | View Download | |||
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