| Synthesis, characterization and ethylene polymerization behavior of binuclear iron complexes bearing N,N '-bis(1-(6-(1-(arylimino)ethyl) pyridin-2-yl)ethylidene)benzidines | |
| Department | OSSO国家重点实验室 |
| Xing QF(邢其锋)1,2; Zhao, Tong1,2; Qiao, Yusen1,2; Wang L(王林)1,2; Redshaw, Carl4; Sun WH(孙文华)1,2,3; Carl Redshaw; Sun WH(孙文华) | |
| 2013 | |
| Source Publication | RSC Advances
 |
| ISSN | 2046-2069 |
| Volume | 3Issue:48Pages:26184-26193 |
| Abstract | A series of N,N′-bis(1-(6-(1-(arylimino)ethyl)pyridin-2-yl)ethylidene)benzidines and the bi-metallic iron complexes thereof have been synthesized and fully characterized. All iron complexes, when activated by MAO or MMAO, exhibited high activities of up to 1.3×107 g mol-1 (Fe) h-1 for the polymerization of ethylene. On comparison with their mononuclear counterparts, such bi-metallic complexes not only retain a relatively high activity at elevated temperatures (up to 70 ℃), but also exhibit increased lifetimes. The polyethylenes obtained were characterized by GPC, DSC and high temperature NMR spectroscopy, which indicated multimodal and highly linear features. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c3ra42631a |
| Funding Organization | National Natural Science Foundation of China (no. 20904059) |
| Indexed By | SCI |
| If | 3.708 |
| Language | 英语 |
| compositor | 第三作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4873 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Carl Redshaw; Sun WH(孙文华) |
| Affiliation | 1.Chinese Acad Sci, Key Lab Engn Plast, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 4.Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England |
| Recommended Citation GB/T 7714 | Xing QF,Zhao, Tong,Qiao, Yusen,et al. Synthesis, characterization and ethylene polymerization behavior of binuclear iron complexes bearing N,N '-bis(1-(6-(1-(arylimino)ethyl) pyridin-2-yl)ethylidene)benzidines[J]. RSC Advances,2013,3(48):26184-26193. |
| APA | Xing QF.,Zhao, Tong.,Qiao, Yusen.,Wang L.,Redshaw, Carl.,...&孙文华.(2013).Synthesis, characterization and ethylene polymerization behavior of binuclear iron complexes bearing N,N '-bis(1-(6-(1-(arylimino)ethyl) pyridin-2-yl)ethylidene)benzidines.RSC Advances,3(48),26184-26193. |
| MLA | Xing QF,et al."Synthesis, characterization and ethylene polymerization behavior of binuclear iron complexes bearing N,N '-bis(1-(6-(1-(arylimino)ethyl) pyridin-2-yl)ethylidene)benzidines".RSC Advances 3.48(2013):26184-26193. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| RSC Adv., 2013, 3, 2（571KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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