| Catalytic Synthesis of Functional Silicon-Stereogenic Silanes through Candida antarctica Lipase B Catalyzed Remote Desymmetrization of Silicon-Centered Diols | |
| Department | OSSO国家重点实验室 |
| Liu X(刘星)1; Li L(李莉)1; Yang W(杨伟)1; Jiang KZ(蒋可志)1; Yang KF(杨科芳)1; Zheng ZJ(郑战江)1; Xu LW(徐利文)1,2; Xu LW(徐利文) | |
| 2013 | |
| Source Publication | European Journal of Organic Chemistry
 |
| ISSN | 1434-193X |
| Volume | 2013Issue:26Pages:5814-5819 |
| Abstract | A series of silicon-containing diols are synthesized and used in lipase-catalyzed remote desymmetrization. This synthetic method is valuable in the construction of optically active silicon-stereogenic organosilicon compounds. Good enantioselectivities of the remote desymmetrization was achieved with Candida antarctica lipase B (CAL-B) (up to 90:10er). |
| Keyword | Asymmetric Catalysis Chirality Silicon Enzymes Diols |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/ejoc.201300932 |
| Funding Organization | the National Natural Science Foundation of China (NSFC) (grant numbers 21173064;21205025);Zhejiang Provincial Natural Science Foundation of China (ZPNSFC) (Q12B020037);the Program for Excellent Young Teachers in Hangzhou Normal University (HNUEYT) (JTAS 2011-01-014) |
| Indexed By | SCI |
| If | 3.154 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4868 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xu LW(徐利文) |
| Affiliation | 1.Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 310012, Zhejiang, Peoples R China 2.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Liu X,Li L,Yang W,et al. Catalytic Synthesis of Functional Silicon-Stereogenic Silanes through Candida antarctica Lipase B Catalyzed Remote Desymmetrization of Silicon-Centered Diols[J]. European Journal of Organic Chemistry,2013,2013(26):5814-5819. |
| APA | Liu X.,Li L.,Yang W.,Jiang KZ.,Yang KF.,...&徐利文.(2013).Catalytic Synthesis of Functional Silicon-Stereogenic Silanes through Candida antarctica Lipase B Catalyzed Remote Desymmetrization of Silicon-Centered Diols.European Journal of Organic Chemistry,2013(26),5814-5819. |
| MLA | Liu X,et al."Catalytic Synthesis of Functional Silicon-Stereogenic Silanes through Candida antarctica Lipase B Catalyzed Remote Desymmetrization of Silicon-Centered Diols".European Journal of Organic Chemistry 2013.26(2013):5814-5819. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Eur. J. Org. Chem. 2（429KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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