| Nitrogen-Functionalized Ordered Mesoporous Carbons as Multifunctional Supports of Ultrasmall Pd Nanoparticles for Hydrogenation of Phenol | |
| Department | OSSO国家重点实验室 |
Li ZL(李泽龙)1,3; Liu JH(刘建华)1 ; Xia CG(夏春谷)1; Li FW(李福伟)1,2; Xia CG(夏春谷); Li FW(李福伟)
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| 2013 | |
| Source Publication | ACS Catalysis
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| ISSN | 2155-5435 |
| Volume | 3Issue:11Pages:2440-2448 |
| Abstract | N-functionalized ordered mesoporous carbons could be readily obtained by post-synthesis treatment with nitrogen containing molecules to achieve materials with a nitrogen loading as high as 8.6 wt % and well preserved mesopore structure. Using NH3 as nitrogen source dramatically increased the Brunauer−Emmett−Teller (BET) surface area and pore volume of the resultant hybrid material; however, Ndoping with melamine as a source resulted in the contrary results. The N-doped carbons were used as supports to immobilize small-sized Pd nanoparticles (PdNPs), which provided a unique platform to investigate the influence of metal nanoparticle size, mesostructural properties, and N-functionalized supports on the selective hydrogenation of phenol to cyclohexanone, an important intermediate in the production of nylon 6 and nylon 66 in the chemical industry. The catalyst with ultrasmall (about 1.2 nm) PdNPs gave the best reaction activity and selectivity under mild conditions. In addition, the present multifunctional catalyst demonstrated excellent catalytic stability and could be used 6 times without loss of product yields. This outstanding catalytic performance could be attributed to the synergetic effects of mesoporous structure, N-functionalized supports, and the stabilized ultrasmall PdNPs. This work might open new avenues for the development of functionalized catalysts with supported ultrasmall metal nanoparticles and hybrid porous support as well as their clean catalyses. |
| Keyword | N-doped Ordered Mesoporous Carbon Hydrogenation Ultrasmall Pd Nanoparticles Heterogeneous Catalysis |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/cs400506q |
| Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21002106;21133011;21373246) |
| Indexed By | SCI |
| If | 7.572 |
| Language | 英语 |
| Funding Project | 均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/4796 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xia CG(夏春谷); Li FW(李福伟) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 2.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Suzhou 215123, Jiangsu, Peoples R China 3.Univ Chinese Acad Sci, Beijing, Peoples R China |
| Recommended Citation GB/T 7714 | Li ZL,Liu JH,Xia CG,et al. Nitrogen-Functionalized Ordered Mesoporous Carbons as Multifunctional Supports of Ultrasmall Pd Nanoparticles for Hydrogenation of Phenol[J]. ACS Catalysis,2013,3(11):2440-2448. |
| APA | Li ZL,Liu JH,Xia CG,Li FW,夏春谷,&李福伟.(2013).Nitrogen-Functionalized Ordered Mesoporous Carbons as Multifunctional Supports of Ultrasmall Pd Nanoparticles for Hydrogenation of Phenol.ACS Catalysis,3(11),2440-2448. |
| MLA | Li ZL,et al."Nitrogen-Functionalized Ordered Mesoporous Carbons as Multifunctional Supports of Ultrasmall Pd Nanoparticles for Hydrogenation of Phenol".ACS Catalysis 3.11(2013):2440-2448. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| ACS Catal.2013, 3, 2（685KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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